2-Methyl-2,3,3a,6a-tetrahydrocyclopenta(b)pyrrole

Base Information

Chemical Name:2-Methyl-2,3,3a,6a-tetrahydrocyclopenta(b)pyrrole
CAS No.:74195-75-8
Molecular Formula:C8H15N
Molecular Weight:125.214
Hs Code.:
DSSTox Substance ID:DTXSID20995666
Nikkaji Number:J78.008A
Mol file:74195-75-8.mol

Synonyms:74195-75-8;BRN 0001225;2-Methyl-2,3,3a,6a-tetrahydrocyclopenta(b)pyrrole;Cyclopenta(b)pyrrole, 2,3,3a,6a-tetrahydro-2-methyl-;2-methyl-1,2,3,3a,4,5,6,6a-octahydrocyclopenta[b]pyrrole;Octahydro-2-methylcyclopenta[b]pyrrole;SCHEMBL13315791;DTXSID20995666;2-Methyloctahydrocyclopenta[b]pyrrole;LS-58207;Cyclopenta[b]pyrrole, octahydro-2-methyl-

Suppliers and Price of 2-Methyl-2,3,3a,6a-tetrahydrocyclopenta(b)pyrrole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 2-Methyl-2,3,3a,6a-tetrahydrocyclopenta(b)pyrrole

Chemical Property:

Vapor Pressure:1.01mmHg at 25°C
Boiling Point:178.1°Cat760mmHg
Flash Point:53.8°C
PSA：12.03000
Density:0.9g/cm³
LogP:1.86570
XLogP3:1.5
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:125.120449483
Heavy Atom Count:9
Complexity:111

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1CC2CCCC2N1

Technology Process of 2-Methyl-2,3,3a,6a-tetrahydrocyclopenta(b)pyrrole

There total 10 articles about 2-Methyl-2,3,3a,6a-tetrahydrocyclopenta(b)pyrrole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 81097-37-2,81176-45-6
cis-N-tosyl-3-methyl-2-azabicyclo<3.3.0>octane

: 74195-75-8
(3aS,6aS)-2-Methyl-octahydro-cyclopenta[b]pyrrole

Guidance literature:: In methanol; for 4.5h; Irradiation;
DOI:10.1021/ja00373a019

Reference yield: 46.0%

: 81097-07-6
cis-1,3a,4,5,6,6a-hexahydro-2-methyl-1-[(4-methylphenyl)sulfonyl]-cyclopenta[b]pyrrole

: 74195-75-8
(3aS,6aS)-2-Methyl-octahydro-cyclopenta[b]pyrrole

Guidance literature:: With sodium bis(2-methoxyethoxy)aluminium dihydride; In toluene;
DOI:10.1021/ja00373a019

Reference yield:

: 285-67-6
Cyclopentene oxide

: 74195-75-8
(3aS,6aS)-2-Methyl-octahydro-cyclopenta[b]pyrrole

Guidance literature:: Multi-step reaction with 5 steps

1: 95 percent / 1.) Mg

2: 1.) phthalimide, triphenylphosphine, diethyl azodicarboxylate, 2.) hydrazine / 1.) THF, 25 deg C, 3 d, 2.) MeOH, reflux, 10 h

3: 69 percent / pyridine

4: 86 percent / PdCl₂*2CH₃CN, benzoquinone, Na₂CO₃, LiCl / tetrahydrofuran / 6 h / Heating

5: 46 percent / sodium bis(2-methoxyethoxy)aluminium hydride / toluene

With pyridine; dichloro bis(acetonitrile) palladium(II); phthalimide; sodium carbonate; magnesium; triphenylphosphine; sodium bis(2-methoxyethoxy)aluminium dihydride; p-benzoquinone; lithium chloride; hydrazine; diethylazodicarboxylate; In tetrahydrofuran; toluene;
DOI:10.1021/ja00373a019