Di-tert-butylmercury(II)

Base Information

Chemical Name:Di-tert-butylmercury(II)
CAS No.:23587-90-8
Molecular Formula:C8H18 Hg
Molecular Weight:314.821
Hs Code.:
Mol file:23587-90-8.mol

Synonyms:Mercury,di-tert-butyl- (8CI); Bis(tert-butyl)mercury; Di-tert-butylmercury

Suppliers and Price of Di-tert-butylmercury(II)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of Di-tert-butylmercury(II)

Chemical Property:

Melting Point:63-64 °C
Boiling Point:°Cat760mmHg
Flash Point:°C
PSA：0.00000
Density:g/cm³
LogP:3.23870

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Di-tert-butylmercury(II)

There total 9 articles about Di-tert-butylmercury(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 507-20-0
tertiary butyl chloride

: mercury dichloride

: 23587-90-8
di-tert-butylmercury

Guidance literature:: With magnesium; In diethyl ether; exclusion of oxygen and moisture; t-butylgrignard compound prepd. from 1.5 mol Mg and 1.2 mol t-BuCl in ether; 0.27 mol of powdered HgCl2 added slowly to 0.58 mol of t-BuMgCl in ether under cooling; mixt. stirred for 12 h at room temp.; addn. of Na-K tartrate for phase sepn.; org. phase sepd. and stirred with hexane; drying over Na2SO4; solvent removed in vac.; residue dissolved in hexane; soln. evapd.; solid sublimated at 40°C in vac.;

Reference yield: 29.0%

: mercury dichloride

: 23587-90-8
di-tert-butylmercury

Guidance literature:: With tert.-butyl lithium; In tetrahydrofuran; pentane; under Ar; addn. of soln. of butyllithium (pentane) to soln. of HgCl2 (THF) at 0°C with stirring; stirred (1 h, 0°C);; addn. of H2O; filtration; concn. to dryness; extd. (pentane); centrifuged; washed (pentane, -78°C); dried (dark, stream of Ar); recrystn. from pentane; elem. anal.;;