6-(Bromomethyl)-1,5,5-trimethylcyclohexene

Base Information

• Chemical Name: 6-(Bromomethyl)-1,5,5-trimethylcyclohexene
• CAS No.: 72152-80-8
• Deprecated CAS: 165066-33-1
• Molecular Formula: C₁₀H₁₇Br
• Molecular Weight: 217.149
• DSSTox Substance ID: DTXSID60888088
• Nikkaji Number: J447.073G
• Mol file: 72152-80-8.mol

Synonyms:72152-80-8;Cyclohexene, 6-(bromomethyl)-1,5,5-trimethyl-;6-(Bromomethyl)-1,5,5-trimethylcyclohexene;DTXSID60888088

Chemical Property of 6-(Bromomethyl)-1,5,5-trimethylcyclohexene

Chemical Property:

• Vapor Pressure: 0.132mmHg at 25°C
• Boiling Point: 225.1°Cat760mmHg
• Flash Point: 86.5°C
• PSA: 0.00000
• Density: 1.14g/cm³
• LogP: 3.76380
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 216.05136
• Heavy Atom Count: 11
• Complexity: 168

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CCCC(C1CBr)(C)C

Technology Process of 6-(Bromomethyl)-1,5,5-trimethylcyclohexene

There total 1 articles about 6-(Bromomethyl)-1,5,5-trimethylcyclohexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ α-cyclogeranyl bromide (72152-80-8,165066-33-1)

Guidance literature:

With pyridine; phosphorus tribromide;

DOI:10.1002/hlca.19500330616

Reference yield:

α-cyclogeranyl bromide (72152-80-8,165066-33-1) → 3-bromomethyl-4,4-dimethyl-2-methylene-cyclohexyl hydroperoxide

Guidance literature:

With oxygen; methylene blue; In dichloromethane; Irradiation;

DOI:10.1055/s-2005-871573

Reference yield:

α-cyclogeranyl bromide (72152-80-8,165066-33-1) → (1R,3S)-3-Bromomethyl-4,4-dimethyl-2-methylene-cyclohexanol

Guidance literature:

Multi-step reaction with 2 steps

1: O₂; methylene blue / CH₂Cl₂ / Irradiation

2: PPh₃ / CH₂Cl₂

With oxygen; methylene blue; triphenylphosphine; In dichloromethane;

DOI:10.1055/s-2005-871573

Downstream raw materials:

1-vinyl-1-methyl-3-<1'-phenylsulfonyl-2'-(2,6,6-trimethylcyclohex-2-enyl)ethyl>cyclohex-3-ene

3-methylene-5-(1',6',6'-trimethyl-2'-cyclohexenyl)-1-pentanol