trans-1,2-Diethyl-cyclopropane

Base Information

• Chemical Name: trans-1,2-Diethyl-cyclopropane
• CAS No.: 71032-66-1
• Molecular Formula: C7H14
• Molecular Weight: 98.1882
• DSSTox Substance ID: DTXSID30991336
• Mol file: 71032-66-1.mol

Synonyms:1,2-diethylcyclopropane;71032-66-1;DTXSID30991336

Chemical Property of trans-1,2-Diethyl-cyclopropane

Chemical Property:

• Vapor Pressure: 56.3mmHg at 25°C
• Boiling Point: 93.4°Cat760mmHg
• Flash Point: °C
• Density: 0.764g/cm³
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 98.109550447
• Heavy Atom Count: 7
• Complexity: 49.1

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CCC1CC1CC

Technology Process of trans-1,2-Diethyl-cyclopropane

There total 14 articles about trans-1,2-Diethyl-cyclopropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trans-1-(2'-toluenesulfonyloxyethyl)-2-ethylcyclopropane → trans-1,2-diethylcyclopropane (71032-66-1)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; at 20 ℃; for 1h;

DOI:10.1021/jo7013356

Reference yield:

trans-3-Hexene (13269-52-8) → trans-1,2-diethylcyclopropane (71032-66-1)

Guidance literature:

With diiodomethane; diethyl ether; coppered zinc;

DOI:10.1021/ja01525a036

Reference yield:

trans-1-(2'-hydroxyethyl)-2-ethylcyclopropane → trans-1,2-diethylcyclopropane (71032-66-1)

Guidance literature:

Multi-step reaction with 2 steps

1: pyridine / CHCl₃ / 0 - 5 °C

2: 0.23 g / lithium aluminum hydride / diethyl ether / 1 h / 20 °C

With pyridine; lithium aluminium tetrahydride; In diethyl ether; chloroform;

DOI:10.1021/jo7013356

upstream raw materials:

diiodomethane

cis-3-hexene

trans-3-Hexene

3-hexene

Downstream raw materials:

n-hexan-3-one

Refernces

• 1、 Wiberg,Lupton Jr.,Wasserman,de Meijere,Kass. "6. 1. 0.". . p. 1740 - 1744. Retrieved 2007/10/02.