Mercury, dichlorobis(triphenylphosphine)-

Base Information

• Chemical Name: Mercury, dichlorobis(triphenylphosphine)-
• CAS No.: 14494-85-0
• Molecular Formula: C36H30 Cl2 Hg P2
• Molecular Weight: 796.078
• NSC Number: 193740
• Mol file: 14494-85-0.mol

Synonyms:Mercury, dichlorobis(triphenylphosphine)-;NSC193740;14494-85-0;NSC-193740;P(c1ccccc1)(c2ccccc2)c3ccccc3.Cl.Cl.c4ccc(cc4)P(c5ccccc5)c6ccccc6

Chemical Property of Mercury, dichlorobis(triphenylphosphine)-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 798.106274
• Heavy Atom Count: 41
• Complexity: 490

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.Cl[Hg]Cl

Technology Process of Mercury, dichlorobis(triphenylphosphine)-

There total 32 articles about Mercury, dichlorobis(triphenylphosphine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

(C5H5)Fe(C5H3(HgCl)C(C6H5)NC6H5) + triphenylphosphine (603-35-0) → HgCl2(triphenylphosphine)2 (14494-85-0) + Hg((C5H5)Fe(C5H3C(C6H5)NC6H5))2 (192519-86-1,192587-70-5) + ((C5H5)Fe(C5H3C(C6H5)NC6H5))Hg(P(C6H5)3)(1+)*Cl(1-)=[((C5H5)Fe(C5H3C(C6H5)NC6H5))Hg(P(C6H5)3)]Cl

Guidance literature:

In chloroform; refluxing equimolar amts. for 0.5 h, standing overnight; concn., chromy. (SiO2); can be recrystallized (CH2Cl2/petroleum ether); elem. anal.;

DOI:10.1016/S0022-328X(96)06602-8

Reference yield: 71.0%

(C5H5)Fe(C5H3(HgCl)C(C6H5)NC6H4CH3) + triphenylphosphine (603-35-0) → HgCl2(triphenylphosphine)2 (14494-85-0) + Hg((C5H5)Fe(C5H3C(C6H5)NC6H4CH3))2 (192587-69-2,192519-84-9) + ((C5H5)Fe(C5H3C(C6H5)NC6H4CH3))Hg(P(C6H5)3)(1+)*Cl(1-)=[((C5H5)Fe(C5H3C(C6H5)NC6H4CH3))Hg(P(C6H5)3)]Cl

Guidance literature:

In chloroform; refluxing equimolar amts. for 0.5 h, standing overnight; concn., chromy. (SiO2); can be recrystallized (CH2Cl2/petroleum ether); elem. anal.;

DOI:10.1016/S0022-328X(96)06602-8

Reference yield: 71.0%

(C5H5)Fe(C5H3(HgCl)C(C6H5)NC6H4CH3) + triphenylphosphine (603-35-0) → HgCl2(triphenylphosphine)2 (14494-85-0) + Hg((C5H5)Fe(C5H3C(C6H5)NC6H4CH3))2 (192519-95-2,192587-74-9) + ((C5H5)Fe(C5H3C(C6H5)NC6H4CH3))Hg(P(C6H5)3)(1+)*Cl(1-)=[((C5H5)Fe(C5H3C(C6H5)NC6H4CH3))Hg(P(C6H5)3)]Cl

Guidance literature:

In chloroform; refluxing equimolar amts. for 0.5 h, standing overnight; concn., chromy. (SiO2); can be recrystallized (CH2Cl2/petroleum ether); elem. anal.;

DOI:10.1016/S0022-328X(96)06602-8

upstream raw materials:

trichlorovinylmercury chloride

methylmercury(II) chloride

triphenylphosphine

(C₆H₅NNC₅H₄N)HgCl₂

Downstream raw materials:

triphenylphosphine borane

Hg⁽²⁺⁾*Cl^(1-)*NO₃^(1-)*P(C₆H₅)3=HgCl(NO₃)(P(C₆H₅)3)

[Hg₂Cl₂(ClO₄)2(8,14,24,30-(Me)4-7,15,23,31-(Ph)4-[1,5,7,9,13,15,17,21,23,25,29,31]dodecaazacyclodotriaconta-8,14,24,30-tetraene)]

3-triphenylphosphine-3-mercura-1,2-dicarbadodecaborane