2,6,10,14-Hexadecatetraenoic acid,3,7,11,15-tetramethyl-,(2E,6E,10E)-

Base Information

• Chemical Name: 2,6,10,14-Hexadecatetraenoic acid,3,7,11,15-tetramethyl-,(2E,6E,10E)-
• CAS No.: 35750-48-2
• Molecular Formula: C₂₀H₃₂O₂
• Molecular Weight: 304.473
• Mol file: 35750-48-2.mol

Synonyms:

Chemical Property of 2,6,10,14-Hexadecatetraenoic acid,3,7,11,15-tetramethyl-,(2E,6E,10E)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,6,10,14-Hexadecatetraenoic acid,3,7,11,15-tetramethyl-,(2E,6E,10E)-

There total 1 articles about 2,6,10,14-Hexadecatetraenoic acid,3,7,11,15-tetramethyl-,(2E,6E,10E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(2E,6E,10E)-3,7,11,15-Tetramethyl-hexadeca-2,6,10,14-tetraenoic acid (E)-1-methyl-3-phenyl-allyl ester (125259-17-8) → (Z,E,E)-3,7,11,15-tetramethyl-2,6,10,14-hexadecatetraenoic acid (35750-48-2) + trans-3-(Methylthio)-1-phenyl-1-butene (40486-72-4)

Guidance literature:

With boron trifluoride diethyl etherate; dimethylthio-dimethyl-tin; acetic acid; Yield given. Multistep reaction. Yields of byproduct given; 1.) toluene, 0 deg C, 24 h, 2.) 0 deg C, 30 min;

DOI:10.1016/S0040-4039(00)99169-X

Reference yield: 94.0%

1-Methylhomopiperazine (4318-37-0) + (Z,E,E)-3,7,11,15-tetramethyl-2,6,10,14-hexadecatetraenoic acid (35750-48-2) → 1-(3,7,11,15-tetramethyl-2,6,10,14-hexadecatetraenoyl)-4-methyl-hexahydro-1,4-diazepine (93494-93-0)

Guidance literature:

Reference yield:

(Z,E,E)-3,7,11,15-tetramethyl-2,6,10,14-hexadecatetraenoic acid (35750-48-2) → methyl (+/-)-(14αH)-isogath-12-en-15-oate (15372-63-1,16633-29-7,54019-59-9,59909-34-1,59909-35-2,82570-42-1,143444-38-6)

Guidance literature:

Multi-step reaction with 2 steps

1: FSO₃H / various solvent(s) / 0.67 h / -55 - -50 °C

With fluorosulphonic acid; In various solvent(s);

DOI:10.1007/BF00630383

upstream raw materials:

(2E,6E,10E)-3,7,11,15-Tetramethyl-hexadeca-2,6,10,14-tetraenoic acid (E)-1-methyl-3-phenyl-allyl ester

Downstream raw materials:

methyl (+/-)-(14αH)-isogath-12-en-15-oate

1-(3,7,11,15-tetramethyl-2,6,10,14-hexadecatetraenoyl)-4-methyl-hexahydro-1,4-diazepine

Refernces