4α-[[2-(Acetylamino)-2-deoxy-4-O-sodiosulfo-β-D-glucopyranosyl]oxy]-5β-(hydroxymethyl)-L-proline

Base Information

Chemical Name:4α-[[2-(Acetylamino)-2-deoxy-4-O-sodiosulfo-β-D-glucopyranosyl]oxy]-5β-(hydroxymethyl)-L-proline
CAS No.:95975-85-2
Molecular Formula:C₁₄H₂₃N₂O₁₂S*Na
Molecular Weight:466.399
Hs Code.:
Mol file:95975-85-2.mol

Synonyms:Substance F3 monosodium salt;Bulgecin C monosodium salt;F3 monosodium salt;

Suppliers and Price of 4α-[[2-(Acetylamino)-2-deoxy-4-O-sodiosulfo-β-D-glucopyranosyl]oxy]-5β-(hydroxymethyl)-L-proline

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 4α-[[2-(Acetylamino)-2-deoxy-4-O-sodiosulfo-β-D-glucopyranosyl]oxy]-5β-(hydroxymethyl)-L-proline

Chemical Property:

PSA：235.88000
LogP:-1.92780

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 4α-[[2-(Acetylamino)-2-deoxy-4-O-sodiosulfo-β-D-glucopyranosyl]oxy]-5β-(hydroxymethyl)-L-proline

There total 25 articles about 4α-[[2-(Acetylamino)-2-deoxy-4-O-sodiosulfo-β-D-glucopyranosyl]oxy]-5β-(hydroxymethyl)-L-proline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 132696-23-2
(2S,4S,5R)-4-<(2-acetamido-4-O-sulfo-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranosyl)oxy>-5-<(benzyloxy)methyl>-1,2-pyrrolidinedicarboxylic acid bis(phenylmethyl ester)

: 95975-85-2
bulgecin C

Guidance literature:: With formic acid; palladium; In methanol; for 0.5h; Ambient temperature;
DOI:10.1021/jo00008a040

Reference yield:

: 129001-57-6
(2S,4S,5R)-4-<(2-acetamido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranosyl)oxy>-5-<(benzyloxy)methyl>-1,2-pyrrolidinedicarboxylic acid bis(phenylmethyl ester)

: 95975-85-2
bulgecin C

Guidance literature:: Multi-step reaction with 2 steps

1: 65 percent / pyridine*SO₃ / dimethylformamide / Ambient temperature

2: 70 percent / 95percent formic acid / Pd black / methanol / 0.5 h / Ambient temperature

With formic acid; sulfur trioxide pyridine complex; palladium; In methanol; N,N-dimethyl-formamide;
DOI:10.1021/jo00008a040

Reference yield:

: 132592-39-3
(2S,4S,5R)-4-<(2-acetamido-4-O-benzoyl-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranosyl)oxy>-5-<(benzyloxy)methyl>-1,2-pyrrolidinedicarboxylic acid bis(phenylmethyl ester)

: 95975-85-2
bulgecin C

Guidance literature:: Multi-step reaction with 3 steps

1: 74 percent / aq. KOH / methanol / Ambient temperature

2: 65 percent / pyridine*SO₃ / dimethylformamide / Ambient temperature

3: 70 percent / 95percent formic acid / Pd black / methanol / 0.5 h / Ambient temperature

With potassium hydroxide; formic acid; sulfur trioxide pyridine complex; palladium; In methanol; N,N-dimethyl-formamide;
DOI:10.1021/jo00008a040