Technology Process of cobaltous methyl 3-[(5Z,10Z,14Z,19Z)-7,12-diethyl-18-(3-methoxy-3-oxo-propyl)-3,8,13,17-tetramethyl-21,23-dihydroporphyrin-2-yl]propanoate
There total 5 articles about cobaltous methyl 3-[(5Z,10Z,14Z,19Z)-7,12-diethyl-18-(3-methoxy-3-oxo-propyl)-3,8,13,17-tetramethyl-21,23-dihydroporphyrin-2-yl]propanoate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
sodium tetrahydroborate; cobalt(II) chloride hexahydrate;
In
dichloromethane; N,N-dimethyl-formamide;
at 25 ℃;
for 0.333333h;
Inert atmosphere;
DOI:10.1002/cjoc.201200581
- Guidance literature:
-
Multi-step reaction with 2 steps
1: N,N-dimethyl-formamide / Reflux
2: sodium tetrahydroborate; cobalt(II) chloride hexahydrate / dichloromethane; N,N-dimethyl-formamide / 0.33 h / 25 °C / Inert atmosphere
With
sodium tetrahydroborate; cobalt(II) chloride hexahydrate;
In
dichloromethane; N,N-dimethyl-formamide;
DOI:10.1002/cjoc.201200581
- Guidance literature:
-
In
acetic acid;
dropwise addition of an airfree hot solution of mesoporphyrinium chloride in acetic acid to a solution of Co(II)-acetate in acetic acid under N2 forms product;; washing with cold airfree acetic acid; drying in vac. over KOH;;
