Technology Process of 2-(1,2,2-Trimethyl-4-oxocyclopentane-1α-yl)-5-methyl-1,4-benzoquinone
There total 17 articles about 2-(1,2,2-Trimethyl-4-oxocyclopentane-1α-yl)-5-methyl-1,4-benzoquinone which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
ammonium cerium(IV) nitrate;
In
water; acetonitrile;
at 20 ℃;
for 1h;
DOI:10.1055/s-2007-967971
- Guidance literature:
-
Multi-step reaction with 2 steps
1: PCC; silica gel / CH2Cl2 / 2 h / 20 °C
2: 95 percent / ceric ammonium nitrate / acetonitrile; H2O / 1 h / 20 °C
With
ammonium cerium(IV) nitrate; silica gel; pyridinium chlorochromate;
In
dichloromethane; water; acetonitrile;
DOI:10.1055/s-2007-967971
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: BH3*Me2S / hexane / 1 h / 0 - 20 °C
1.2: aq. NaOH; aq. H2O2 / 5 h / 0 - 20 °C
2.1: 96 percent / pyridinium chlorochromate; silica gel / CH2Cl2 / 2 h / 20 °C
3.1: 94 percent / ceric ammonium nitrite / acetonitrile; H2O / 1 h / 20 °C
With
ammonium cerium(IV) nitrate; dimethylsulfide borane complex; silica gel; pyridinium chlorochromate;
In
hexane; dichloromethane; water; acetonitrile;
DOI:10.1016/j.tetlet.2005.12.071
