2-(6-carboxyhexyl)cyclopentanone hexylhydrazone

Base Information

• Chemical Name: 2-(6-carboxyhexyl)cyclopentanone hexylhydrazone
• CAS No.: 85421-76-7
• Molecular Formula: C₁₈H₃₄N₂O₂
• Molecular Weight: 310.48
• Mol file: 85421-76-7.mol

Synonyms:Cyclopentaneheptanoicacid, 2-(hexylhydrazono)- (9CI)

Chemical Property of 2-(6-carboxyhexyl)cyclopentanone hexylhydrazone

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 2-(6-carboxyhexyl)cyclopentanone hexylhydrazone

There total 4 articles about 2-(6-carboxyhexyl)cyclopentanone hexylhydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

2-(6-carboxyhexyl)cyclopentanone (5288-67-5) + n-hexylhydrazine hydrochloride (79201-41-5) → 2-(6-carboxyhexyl)cyclopentanone hexylhydrazone (85421-76-7)

Guidance literature:

With sodium acetate; In methanol; at 4 ℃;

DOI:10.1021/jm00361a020

Reference yield:

hexanal (66-25-1) → 2-(6-carboxyhexyl)cyclopentanone hexylhydrazone (85421-76-7)

Guidance literature:

Multi-step reaction with 4 steps

1: 93 percent / hexane / 0.33 h / Heating

2: BH₃*THF / 0.17 h

3: 6N HCl / 0.17 h / Heating

4: 59 percent / NaOAc / methanol / 4 °C

With hydrogenchloride; borane-THF; sodium acetate; In methanol; hexane;

DOI:10.1021/jm00361a020

Reference yield:

tert-butyl 2-hexylidenehydrazinecarboxylate (79201-37-9) → 2-(6-carboxyhexyl)cyclopentanone hexylhydrazone (85421-76-7)

Guidance literature:

Multi-step reaction with 3 steps

1: BH₃*THF / 0.17 h

2: 6N HCl / 0.17 h / Heating

3: 59 percent / NaOAc / methanol / 4 °C

With hydrogenchloride; borane-THF; sodium acetate; In methanol;

DOI:10.1021/jm00361a020

upstream raw materials:

2-(6-carboxyhexyl)cyclopentanone

n-hexylhydrazine hydrochloride

hexanal

tert-butyl 2-hexylidenehydrazinecarboxylate

Refernces