4-{(z)-[4-(Acetyloxy)phenyl]-nno-azoxy}phenyl acetate

Base Information

• Chemical Name: 4-{(z)-[4-(Acetyloxy)phenyl]-nno-azoxy}phenyl acetate
• CAS No.: 79030-44-7
• Molecular Formula: C16H14N2O5
• Molecular Weight: 314.298
• NSC Number: 96516
• DSSTox Substance ID: DTXSID10294413
• Mol file: 79030-44-7.mol

Synonyms:4-{(z)-[4-(acetyloxy)phenyl]-nno-azoxy}phenyl acetate;79030-44-7;NSC96516;(4-acetyloxyphenyl)-(4-acetyloxyphenyl)imino-oxidoazanium;DTXSID10294413;NSC-96516

Chemical Property of 4-{(z)-[4-(Acetyloxy)phenyl]-nno-azoxy}phenyl acetate

Chemical Property:

• Vapor Pressure: 4.38E-09mmHg at 25°C
• Boiling Point: 472.2°Cat760mmHg
• Flash Point: 239.4°C
• Density: 1.24g/cm³
• XLogP3: 2.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 6
• Exact Mass: 314.09027155
• Heavy Atom Count: 23
• Complexity: 449

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)OC1=CC=C(C=C1)N=[N+](C2=CC=C(C=C2)OC(=O)C)[O-]

Technology Process of 4-{(z)-[4-(Acetyloxy)phenyl]-nno-azoxy}phenyl acetate

There total 3 articles about 4-{(z)-[4-(Acetyloxy)phenyl]-nno-azoxy}phenyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

4-nitrophenol acetate (830-03-5) → 4,4'-diacetoxyazoxybenzene (79030-44-7)

Guidance literature:

With oxygen; ammonium chloride; zinc; In [bmim][BF₄]; water; at 20 ℃; for 17h;

DOI:10.1016/j.tetlet.2009.02.122

Reference yield:

bis-(4-acetoxy-phenyl)-diazene (132466-19-4) → 4,4'-diacetoxyazoxybenzene (79030-44-7)

Guidance literature:

With dihydrogen peroxide; acetic acid; at 70 - 80 ℃;

DOI:10.1557/JMR.2002.0158

Reference yield:

acetic anhydride (108-24-7) + 4,4'-dihydroxyazoxybenzene (15596-57-3,117823-25-3) → 4,4'-diacetoxyazoxybenzene (79030-44-7)

Guidance literature:

With pyridine;

DOI:10.1021/jo50008a001

upstream raw materials:

acetic anhydride

4,4'-dihydroxyazoxybenzene

4-nitrophenol acetate

bis-(4-acetoxy-phenyl)-diazene

Downstream raw materials:

4,4'-dihydroxyazoxybenzene

benzene-1,4-diyl diacetate

4-acetoxyphenyl tosylate