Palladium(2+);pentane-2,4-dione

Base Information

• Chemical Name: Palladium(2+);pentane-2,4-dione
• CAS No.: 14024-61-4
• Molecular Formula: C10H14O4Pd
• Molecular Weight: 304.64
• Hs Code.: 28439090
• Mol file: 14024-61-4.mol

Synonyms:SCHEMBL4519684

Chemical Property of Palladium(2+);pentane-2,4-dione

Chemical Property:

• Appearance/Colour: yellow orange needles
• Vapor Pressure: 0.174mmHg at 25°C
• Melting Point: 190 °C
• Boiling Point: 138.4 °C at 760 mmHg
• Flash Point: 43.1 °C
• PSA: 68.28000
• LogP: 1.10900
• Storage Temp.: Store below +30°C.
• Solubility.: Soluble in benzene and chloroform.
• Water Solubility.: INSOLUBLE
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 4
• Exact Mass: 303.99269
• Heavy Atom Count: 15
• Complexity: 196

Purity/Quality:

99% ^*data from raw suppliers

Palladium(II) acetylacetonate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn, Xi
• Hazard Codes: Xi,Xn
• Statements: 36-36/37/38-22
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=O)[CH-]C(=O)C.CC(=O)[CH-]C(=O)C.[Pd+2]
• General Description: Bis(2,4-pentanedionato-O,O')palladium(II), also known as palladium(II) acetylacetonate or Pd(acac)2, is a coordination compound where palladium(II) is chelated by two acetylacetonate (acac) ligands through their oxygen atoms. This yellow crystalline solid is widely used as a precursor in catalysis, materials science, and organic synthesis due to its stability and solubility in organic solvents. It serves as a key reagent in cross-coupling reactions, nanoparticle synthesis, and thin-film deposition processes. Bis(2,4-pentanedionato-O,O')palladium(II)’s square-planar geometry and mild reactivity make it valuable for controlled Pd-mediated transformations.

Refernces

REACTIONS OF DIAZOALKANES WITH UNSATURATED COMPOUNDS. 6. CATALYTIC CYCLOPROPANATION OF UNSATURATED HYDROCARBONS AND THEIR DERIVATIVES WITH DIAZOMETHANE

10.1007/BF00956960

The research investigates the catalytic cyclopropanation of various unsaturated compounds with diazomethane (DAM), using a range of transition metal, nontransition metal, and rare earth metal compounds as catalysts. The study explores the effects of different catalysts, solvents, and reaction conditions on the yields of cyclopropane products. Key chemicals involved include DAM, various olefins such as norbornene, and catalysts like Pd(acac)2, Ni(acac)2, and Cu(acac)2. The research also examines the influence of ligand additives and the nature of the double bond in different unsaturated compounds on the cyclopropanation process. The findings reveal that Pd(acac)2 is highly active for cyclopropanation, and the yields of cyclopropane products can be significantly affected by the choice of solvent and the presence of electron-donating ligands. The study provides valuable insights into optimizing the cyclopropanation process for various unsaturated compounds.

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