(NE)-N-[(E)-4-(furan-2-yl)but-3-en-2-ylidene]hydroxylamine

Base Information

Chemical Name:(NE)-N-[(E)-4-(furan-2-yl)but-3-en-2-ylidene]hydroxylamine
CAS No.:6502-39-2
Molecular Formula:C8H9NO2
Molecular Weight:151.165
Hs Code.:
NSC Number:236257
DSSTox Substance ID:DTXSID20421076

Synonyms:6502-39-2;NSC236257;(NE)-N-[(E)-4-(furan-2-yl)but-3-en-2-ylidene]hydroxylamine;3-Buten-2-one, 4-(2-furanyl)-, oxime, (Z,E)-;65300-32-5;DTXSID20421076;NSC-236257;EN300-246482

Suppliers and Price of (NE)-N-[(E)-4-(furan-2-yl)but-3-en-2-ylidene]hydroxylamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
N-[4-(furan-2-yl)but-3-en-2-ylidene]hydroxylamine
250mg
$ 330.00

TRC
N-[4-(furan-2-yl)but-3-en-2-ylidene]hydroxylamine
25mg
$ 65.00

Total 7 raw suppliers

Chemical Property of (NE)-N-[(E)-4-(furan-2-yl)but-3-en-2-ylidene]hydroxylamine

Chemical Property:

Vapor Pressure:0.003mmHg at 25°C
Refractive Index:1.51
Boiling Point:274.311 °C at 760 mmHg
Flash Point:119.699 °C
PSA：45.73000
Density:1.07 g/cm³
LogP:2.14290
XLogP3:1.6
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:151.063328530
Heavy Atom Count:11
Complexity:175

Purity/Quality:

99% ^*data from raw suppliers

N-[4-(furan-2-yl)but-3-en-2-ylidene]hydroxylamine ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=NO)C=CC1=CC=CO1
Isomeric SMILES:C/C(=N\O)/C=C/C1=CC=CO1

Technology Process of (NE)-N-[(E)-4-(furan-2-yl)but-3-en-2-ylidene]hydroxylamine

There total 5 articles about (NE)-N-[(E)-4-(furan-2-yl)but-3-en-2-ylidene]hydroxylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 623-15-4
(E)-4-(furan-2-yl)but-3-en-2-one

: 6502-39-2,65300-31-4,65300-32-5
4t-[2]furyl-but-3-en-2-one oxime

Guidance literature:: With hydroxylamine;
DOI:10.1021/ja01857a077

Reference yield:

: 623-15-4
4-(furan-2-yl)but-3-en-2-one

: 6502-39-2
4-furan-2-yl-but-3-en-2-one oxime

Guidance literature:: With hydroxylamine hydrochloride; sodium acetate; In ethanol; water; at 100 ℃; for 6h;
DOI:10.1021/acs.orglett.1c03679

Reference yield:

: 79380-04-4,1141893-14-2
3-(2-furyl)-1-methylallyl alcohol

: 6502-39-2,65300-31-4,65300-32-5
4t-[2]furyl-but-3-en-2-one oxime

Guidance literature:: Multi-step reaction with 2 steps

1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; oxygen / tert-butyl methyl ether / 16 h / 30 °C / pH 5 / Enzymatic reaction

2: sodium hydroxide; hydroxylamine hydrochloride / water; ethanol / Reflux

With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; hydroxylamine hydrochloride; oxygen; sodium hydroxide; In ethanol; tert-butyl methyl ether; water;
DOI:10.1002/cbic.201900473