iodo-triphenylphosphoranylidene-cobalt, oxoazanide

Base Information

Chemical Name:iodo-triphenylphosphoranylidene-cobalt, oxoazanide
CAS No.:14318-98-0
Molecular Formula:C18H15 Co I N2 O2 P
Molecular Weight:0
Hs Code.:
Mol file:14318-98-0.mol

Synonyms:Cobalt,iododinitrosyl(triphenylphosphine)- (7CI,8CI);Iododinitrosyl(triphenylphosphine)cobalt

Suppliers and Price of iodo-triphenylphosphoranylidene-cobalt, oxoazanide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of iodo-triphenylphosphoranylidene-cobalt, oxoazanide

Chemical Property:

PSA：47.73000
LogP:1.09320

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of iodo-triphenylphosphoranylidene-cobalt, oxoazanide

There total 3 articles about iodo-triphenylphosphoranylidene-cobalt, oxoazanide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 44387-12-4
dinitroso-cobalt(III) iodide

: 14318-98-0
iododinitrosyl(triphenylphosphine)cobalt

Guidance literature:: With triphenylphosphine; In acetone; under N2, soln. of Co-compd. and PPh3 in acetone refluxed for 1 h; according to Heiber, W.; Heinecke, K. Z. Anorg. Allg. Chem. 1962, 316, 305; filtered, abs. EtOH added, vol. reduced by rotary evapn., stood for about 1 h, filtered, hexane added to mother liquor, coold to 0°C (second crop); elem. anal.;

Reference yield:

: dinitrosylbis(triphenylphosphine)cobalt hexafluorophosphate

: 68-05-3
tetraethylammonium iodide

: 14318-98-0
iododinitrosyl(triphenylphosphine)cobalt

Guidance literature:: In tetrahydrofuran; N2-atmosphere; refluxing for 2 h; filtration, evapn., recrystn. (hot hexane); elem. anal.;
DOI:10.1039/DT9770002085

Reference yield:

: {Co(CO)(NO)(P(C₆H₅)3)2}

: 14318-98-0
iododinitrosyl(triphenylphosphine)cobalt

Guidance literature:: Multi-step reaction with 2 steps

1: methanol; benzene

2: dichloromethane

In methanol; dichloromethane; benzene;
DOI:10.1039/DT9770002085