2-Azidofluorene

Base Information

• Chemical Name: 2-Azidofluorene
• CAS No.: 67823-52-3
• Molecular Formula: C13H9N3
• Molecular Weight: 207.235
• UNII: 55QQF1834L
• DSSTox Substance ID: DTXSID90218071
• Nikkaji Number: J489.743I
• Wikidata: Q27261336
• Mol file: 67823-52-3.mol

Synonyms:2-azidofluorene

Chemical Property of 2-Azidofluorene

Chemical Property:

• PSA: 49.75000
• LogP: 3.65236
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 207.079647300
• Heavy Atom Count: 16
• Complexity: 308

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1C2=CC=CC=C2C3=C1C=C(C=C3)N=[N+]=[N-]

Technology Process of 2-Azidofluorene

There total 2 articles about 2-Azidofluorene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

2-aminofluorene (153-78-6) → 2-azido-9H-fluorene (67823-52-3)

Guidance literature:

2-aminofluorene; With trifluoroacetic acid; sodium nitrite;

With sodium azide;

DOI:10.1021/acs.orglett.5b02290

Reference yield: 95.0%

9H-fluorene-2-diazonium tetrafluoroborate → 2-azido-9H-fluorene (67823-52-3)

Guidance literature:

With trimethylsilylazide; In N,N-dimethyl-formamide; for 1h; Ambient temperature;

DOI:10.1246/bcsj.62.89

Reference yield: 90.0%

methyl phenylphosphinate (7162-15-4,111469-75-1,121467-78-5) + 2-azido-9H-fluorene (67823-52-3) → methyl N-9H-fluoren-2-yl-P-phenylphosphonamidate (1262801-03-5)

Guidance literature:

methyl phenylphosphinate; 2-azido-9H-fluorene; With bis-(trimethylsilyl)acetamide; In acetonitrile; at 20 ℃;

With tetrabutyl ammonium fluoride; In acetonitrile; at 20 ℃; for 0.5h;

DOI:10.1039/c0cc02472d

upstream raw materials:

2-aminofluorene

Downstream raw materials:

2-fluoren

C₃₅H₂₃N₃O₂

C₃₉H₃₃N₄O⁽¹⁺⁾*Cl^(1-)

C₃₅H₂₄N₄O