(4S)-C(14a)-Homo-27-norgammacer-14-ene-3β,21α,24-triol

Base Information

• Chemical Name: (4S)-C(14a)-Homo-27-norgammacer-14-ene-3β,21α,24-triol
• CAS No.: 13956-52-0
• Molecular Formula: C30H50O3
• Molecular Weight: 458.72
• Mol file: 13956-52-0.mol

Synonyms:

Chemical Property of (4S)-C(14a)-Homo-27-norgammacer-14-ene-3β,21α,24-triol

Chemical Property:

• Melting Point: 335-336 °C
• Boiling Point: 566.1±50.0 °C(Predicted)
• PKA: 14.93±0.70(Predicted)
• PSA: 60.69000
• Density: 1.10±0.1 g/cm3(Predicted)
• LogP: 6.11210

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (4S)-C(14a)-Homo-27-norgammacer-14-ene-3β,21α,24-triol

There total 5 articles about (4S)-C(14a)-Homo-27-norgammacer-14-ene-3β,21α,24-triol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C41H58O8S (56218-40-7) → serratriol (13956-52-0)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran;

DOI:10.1248/cpb.23.264

Reference yield:

21-Epilycocryptol 3,24-Diacetat (56218-43-0) → serratriol (13956-52-0)

Guidance literature:

Multi-step reaction with 3 steps

1: Py

2: aq. CrO₃, H₂SO₄ / acetone

3: LiAlH₄ / tetrahydrofuran

With pyridine; chromium(VI) oxide; lithium aluminium tetrahydride; sulfuric acid; In tetrahydrofuran; acetone;

DOI:10.1248/cpb.23.264

Reference yield:

C37H58O6 → serratriol (13956-52-0)

Guidance literature:

Multi-step reaction with 4 steps

1: aq. AcOH / CHCl₃; methanol

2: Py

3: aq. CrO₃, H₂SO₄ / acetone

4: LiAlH₄ / tetrahydrofuran

With pyridine; chromium(VI) oxide; lithium aluminium tetrahydride; sulfuric acid; acetic acid; In tetrahydrofuran; methanol; chloroform; acetone;

DOI:10.1248/cpb.23.264

upstream raw materials:

C₄₁H₅₈O₈S

21-Epilycocryptol 3,24-Diacetat

Refernces