GERANYLBENZOQUINONE

Base Information

• Chemical Name: GERANYLBENZOQUINONE
• CAS No.: 61977-06-8
• Molecular Formula: C16H20 O2
• Molecular Weight: 244.33
• Hs Code.: 2914690090
• Mol file: 61977-06-8.mol

Synonyms:2,5-Cyclohexadiene-1,4-dione,2-(3,7-dimethyl-2,6-octadienyl)-, (E)-; 2,5-Cyclohexadiene-1,4-dione,2-[(2E)-3,7-dimethyl-2,6-octadienyl]- (9CI); Geranyl quinone

Chemical Property of GERANYLBENZOQUINONE

Chemical Property:

• Vapor Pressure: 2.9E-05mmHg at 25°C
• Boiling Point: 356.6°C at 760 mmHg
• Flash Point: 133.8°C
• PSA: 34.14000
• Density: 1.015g/cm³
• LogP: 3.70360

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of GERANYLBENZOQUINONE

There total 13 articles about GERANYLBENZOQUINONE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

(E)-2-(3,7-dimethylocta-2,6-dien-1-yl)-4-methoxyphenol (79233-10-6) → (E)-3,7-dimethylocta-2,6-dienyl-p-benzoquinone (61977-06-8)

Guidance literature:

With ammonium cerium (IV) nitrate; In water; acetonitrile; at 0 ℃; for 20h;

DOI:10.1021/np300790g

Reference yield: 42.0%

(E)-2-(3,7-dimethylocta-2,6-dienyl)benzene-1,4-diol (10457-66-6) → (E)-3,7-dimethylocta-2,6-dienyl-p-benzoquinone (61977-06-8) + 2-((2E,6E)-8-Hydroxy-3,7-dimethyl-octa-2,6-dienyl)-[1,4]benzoquinone (137362-28-8) + 2-((E)-4-Hydroxy-3,7-dimethyl-octa-2,6-dienyl)-[1,4]benzoquinone (137362-29-9) + (2E,6E)-8-(3,6-Dioxo-cyclohexa-1,4-dienyl)-2,6-dimethyl-octa-2,6-dienal (50801-25-7)

Guidance literature:

With tert.-butylhydroperoxide; selenium(IV) oxide; salicylic acid; In dichloromethane; for 24h; Ambient temperature;

DOI:10.1039/c39910001303

Reference yield:

(E)-2-(3,7-dimethylocta-2,6-dienyl)benzene-1,4-diol (10457-66-6) → (E)-3,7-dimethylocta-2,6-dienyl-p-benzoquinone (61977-06-8)

Guidance literature:

With silver(l) oxide;

DOI:10.1016/j.ejmech.2016.06.036

upstream raw materials:

(E)-2-(3,7-dimethylocta-2,6-dienyl)benzene-1,4-diol

2-((E)-3,7-Dimethyl-octa-2,6-dienyl)-benzene-1,4-diol

geranyl trimethylstannane

p-benzoquinone

Downstream raw materials:

(E)-2-(3,7-dimethylocta-2,6-dienyl)benzene-1,4-diol