2H-1-Benzopyran-3-ol, octahydro-3-methyl-2-(2-nonenyl)-, formate, (2alpha(E),3beta,4aalpha,8abeta)-

Base Information

Chemical Name:2H-1-Benzopyran-3-ol, octahydro-3-methyl-2-(2-nonenyl)-, formate, (2alpha(E),3beta,4aalpha,8abeta)-
CAS No.:101859-11-4
Molecular Formula:C₂₀H₃₄O₃
Molecular Weight:322.488
Hs Code.:

Synonyms:101859-11-4;2H-1-Benzopyran-3-ol, octahydro-3-methyl-2-(2-nonenyl)-, formate, (2alpha(E),3beta,4aalpha,8abeta)-

Suppliers and Price of 2H-1-Benzopyran-3-ol, octahydro-3-methyl-2-(2-nonenyl)-, formate, (2alpha(E),3beta,4aalpha,8abeta)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2H-1-Benzopyran-3-ol, octahydro-3-methyl-2-(2-nonenyl)-, formate, (2alpha(E),3beta,4aalpha,8abeta)-

Chemical Property:

Vapor Pressure:7.66E-07mmHg at 25°C
Boiling Point:407.2°Cat760mmHg
Flash Point:172.6°C
Density:0.99g/cm³
XLogP3:5.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:9
Exact Mass:322.25079494
Heavy Atom Count:23
Complexity:377

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCCCCC=CCC1C(CC2CCCCC2O1)OC(=O)C
Isomeric SMILES:CCCCCC/C=C/C[C@H]1[C@@H](C[C@@H]2CCCC[C@H]2O1)OC(=O)C

Technology Process of 2H-1-Benzopyran-3-ol, octahydro-3-methyl-2-(2-nonenyl)-, formate, (2alpha(E),3beta,4aalpha,8abeta)-

There total 1 articles about 2H-1-Benzopyran-3-ol, octahydro-3-methyl-2-(2-nonenyl)-, formate, (2alpha(E),3beta,4aalpha,8abeta)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 101915-78-0
(8R*)-8-((1S*,3E)-1-iodo-3-decenyl)-8-methyl-7-oxabicyclo<4.3.0>nonane

: 68-12-2,33513-42-7
N,N-dimethyl-formamide

: 101859-11-4
(1R*,3S*,4R*,6S*)-3-((2E)-2-nonenyl)-4-methyl-2-oxabicyclo<4.4.0>dec-4-yl formate

Guidance literature:: With silver tetrafluoroborate; water; at 21 ℃; for 23h;
DOI:10.1021/jo00362a014

Reference yield: 96.0%

: 101859-11-4
(1R*,3S*,4R*,6S*)-3-((2E)-2-nonenyl)-4-methyl-2-oxabicyclo<4.4.0>dec-4-yl formate

: 101859-12-5
(1R*,3S*,4R*,6S*)-3-((2E)-2-nonenyl)-4-methyl-2-oxabicyclo<4.4.0>dec-4-ol

Guidance literature:: With sodium hydroxide; In tetrahydrofuran; at 21 ℃; for 13h;
DOI:10.1021/jo00362a014

Reference yield:

: 101859-11-4
(1R*,3S*,4R*,6S*)-3-((2E)-2-nonenyl)-4-methyl-2-oxabicyclo<4.4.0>dec-4-yl formate

: 101859-14-7
(1R*,3S*,5R*,6S*8R*,10S*)-6-hexyl-8-methyl-2,7-dioxatricyclo<8.4.0.0^3,8>tetradec-5-yl formate

Guidance literature:: Multi-step reaction with 3 steps

1: 96 percent / aq. NaOH / tetrahydrofuran / 13 h / 21 °C

2: 64 percent / I₂ / acetonitrile / 3.5 h / 0 °C

3: 1.) AgBF₄, 2.) H₂O / 27 h / 75 °C

With sodium hydroxide; silver tetrafluoroborate; water; iodine; In tetrahydrofuran; acetonitrile;
DOI:10.1021/jo00362a014