10-Mercaptopinane

Base Information

Chemical Name:10-Mercaptopinane
CAS No.:6588-78-9
Molecular Formula:C₁₀H₁₈S
Molecular Weight:170.319
Hs Code.:
European Community (EC) Number:229-520-8
UNII:79T12O1XFD
DSSTox Substance ID:DTXSID80884320
Nikkaji Number:J225.205H
Wikidata:Q27266773
Mol file:6588-78-9.mol

Synonyms:10-Mercaptopinane;6588-78-9;10-Pinanethiol;6,6-dimethylbicyclo[3.1.1]heptane-2-methanethiol;UNII-79T12O1XFD;Bicyclo[3.1.1]heptane-2-methanethiol, 6,6-dimethyl-;79T12O1XFD;6,6-Dimethylbicyclo(3.1.1)heptane-2-methanethiol;EINECS 229-520-8;Bicyclo(3.1.1)heptane-2-methanethiol, 6,6-dimethyl-;{6,6-DIMETHYLBICYCLO[3.1.1]HEPTAN-2-YL}METHANETHIOL;pinane-10-thiol;SCHEMBL4234069;DTXSID80884320;(+/-)-10-MERCAPTOPINANE;10-MERCAPTOPINANE, (+/-)-;FEMA NO. 3503, 10-MERCAPTO-;EN300-1810135;(6,6-dimethyl-2-bicyclo[3.1.1]heptanyl)methanethiol;(7,7-dimethyl-2-bicyclo[3.1.1]heptanyl)methanethiol;Q27266773;(6,6-Dimethylbicyclo[3.1.1]hept-2-yl)methanethiol #

Suppliers and Price of 10-Mercaptopinane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 6 raw suppliers

Chemical Property of 10-Mercaptopinane

Chemical Property:

Vapor Pressure:0.122mmHg at 25°C
Boiling Point:226.6°C at 760 mmHg
Flash Point:89.4°C
Density:0.952g/cm³
XLogP3:3.5
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:170.11292175
Heavy Atom Count:11
Complexity:162

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1(C2CCC(C1C2)CS)C

Technology Process of 10-Mercaptopinane

There total 5 articles about 10-Mercaptopinane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

: 87727-48-8
myrtanyl tosylate

: 6588-78-9
[6,6-dimethylbicyclo[3.1.1]heptan-2-yl]methanethiol

Guidance literature:: myrtanyl tosylate; With thiourea; In isopropyl alcohol; at 100 ℃; for 15h;

With sodium hydroxide; In isopropyl alcohol; at 100 ℃; for 2h;
DOI:10.1080/10426507.2013.819867

Reference yield: 37.0%

: 139165-46-1
S-[(1S,2R,5S)-6,6-dimethylbicyclo[3.1.1]heptan-2-yl]methyl ethanethioate

: 6588-78-9
[6,6-dimethylbicyclo[3.1.1]heptan-2-yl]methanethiol

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether; for 2h; Reflux; Inert atmosphere;
DOI:10.1080/10426507.2013.819867

Reference yield:

: 51152-12-6
(-)-cis-myrtanol

: 6588-78-9
[6,6-dimethylbicyclo[3.1.1]heptan-2-yl]methanethiol

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine

2: dimethyl sulfoxide

3: lithium aluminium tetrahydride / diethyl ether

With pyridine; lithium aluminium tetrahydride; In diethyl ether; dimethyl sulfoxide;
DOI:10.1039/c5ra14072b