9-ANTHRACENECARBONYL CHLORIDE

Base Information

• Chemical Name: 9-ANTHRACENECARBONYL CHLORIDE
• CAS No.: 16331-52-5
• Molecular Formula: C15H9ClO
• Molecular Weight: 240.689
• Hs Code.: 2916190090
• Mol file: 16331-52-5.mol

Synonyms:9-Anthroylchloride (8CI);9-(Chlorocarbonyl)anthracene;9-Anthracenoyl chloride;9-Anthranoyl chloride;Anthracene-9-carboxylic acid chloride;

Chemical Property of 9-ANTHRACENECARBONYL CHLORIDE

Chemical Property:

• Vapor Pressure: 6.02E-07mmHg at 25°C
• Melting Point: 51 °C
• Refractive Index: 1.713
• Boiling Point: 410.5 °C at 760 mmHg
• Flash Point: 200.8 °C
• PSA: 17.07000
• Density: 1.307 g/cm³
• LogP: 4.37200

Purity/Quality:

97% ^*data from raw suppliers

Anthracene-9-carbonyl chloride 95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Anthracene-9-carbonyl Chloride can be used for enhancement of selectivity of imprinted polymers.

Technology Process of 9-ANTHRACENECARBONYL CHLORIDE

There total 4 articles about 9-ANTHRACENECARBONYL CHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

anthracen-9-carboxylic acid (723-62-6) → 9-anthracenecarbonyl chloride (16331-52-5)

Guidance literature:

With thionyl chloride; for 3h; Heating;

DOI:10.1016/j.tet.2004.01.070

Reference yield:

anthracen-9-carboxylic acid (723-62-6) → 9-anthracenecarbonyl chloride (16331-52-5) + 10-chloroanthracene-9-carbonyl chloride

Guidance literature:

With thionyl chloride; In chloroform; at 80 ℃; for 8h;

DOI:10.1021/jm9016174

Reference yield:

9-anthracene aldehyde (642-31-9) → 9-anthracenecarbonyl chloride (16331-52-5)

Guidance literature:

Multi-step reaction with 2 steps

1: tert.-butylhydroperoxide; selenium(IV) oxide / tert-butyl alcohol / 75 °C

2: 1,3,5-trichloro-2,4,6-triazine; triethylamine / acetone / 1 h / 20 °C

With tert.-butylhydroperoxide; selenium(IV) oxide; 1,3,5-trichloro-2,4,6-triazine; triethylamine; In acetone; tert-butyl alcohol;

DOI:10.24820/ark.5550190.p010.637

upstream raw materials:

anthracen-9-carboxylic acid

9-anthracene aldehyde

Downstream raw materials:

C₄₈H₃₃OP

C₄₈H₃₃OP

anthracene-9-carboxylic acid methyl ester

1,2-bis(9-anthryl)acetylene