Pentaammineaquocobalt(III)

Base Information

• Chemical Name: Pentaammineaquocobalt(III)
• CAS No.: 14403-82-8
• Molecular Formula: CoH17 N5 O
• Molecular Weight: 162.161
• DSSTox Substance ID: DTXSID10162603
• Mol file: 14403-82-8.mol

Synonyms:PAACoTFB;pentaammineaquocobalt(III);pentaammineaquocobalt(III) tetrafluoroborate;pentaammineaquocobalt(III) tribromide;pentaammineaquocobalt(III) trichloride

Chemical Property of Pentaammineaquocobalt(III)

Chemical Property:

• Vapor Pressure: 5990mmHg at 25°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 25.43000
• Density: g/cm³
• LogP: 1.55520
• Hydrogen Bond Donor Count: 6
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 0
• Exact Mass: 162.076504
• Heavy Atom Count: 7
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: N.N.N.N.N.O.[Co+3]

Technology Process of Pentaammineaquocobalt(III)

There total 12 articles about Pentaammineaquocobalt(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

pentammine carbonato cobalt(III) nitrate + (4-hydroxyphenyl)phosphoric acid (940-75-0) → pentaammineaquacobalt(III) (14403-82-8) + (4-hydroxyphenyl phosphato)pentaamminecobalt(III) ion (80964-53-0)

Guidance literature:

In water; byproducts: CO2; Co complex adding to a stirred soln. of ligand in water at room temp., after 1 h a few water adding, heating at 65-70°C for 1.5 h; colorchanging from red-orange to deep red, CO2 ceasing for 0.5 h; cooling toroom temp., diluting with water; purified by chromy. on anion-exchange resin eluting with 0.05 M LiClO4;identified by UV spectra at various pH;

DOI:10.1021/ic00135a081

Reference yield:

succinimido-N-pentaamminecobalt(III) perchlorate salt (136545-45-4) → Succinimide (123-56-8,89963-74-6) + pentaammineaquacobalt(III) (14403-82-8)

Guidance literature:

In water; in acidid soln., very slow;

Reference yield:

{(NH3)5CoOC(CH2)2CON}(2+)*2(CF3SO3)(1-)*H2O=C2F6S2O6N5H15CoOC3H4CONH2O (136545-43-2) → Succinimide (123-56-8,89963-74-6) + pentaammineaquacobalt(III) (14403-82-8)

Guidance literature:

In dimethyl sulfoxide; Kinetics;

upstream raw materials:

water

pentaammineformatocobalt(III) perchlorate

succinimido-N-pentaamminecobalt(III) perchlorate salt

{(NH₃)5CoOC(CH₂)2CON}⁽²⁺⁾*2(CF₃SO₃)^(1-)*H₂O=C₂F₆S₂O₆N₅H₁₅CoOC₃H₄CONH₂O

Downstream raw materials:

cobalt(II)

ruthenium(III)