ethyl(phenyl)carbamodithioic acid

Base Information

• Chemical Name: ethyl(phenyl)carbamodithioic acid
• CAS No.: 19779-48-7
• Molecular Formula: C9H11 N S2 . H3 N
• Molecular Weight: 214.356
• Mol file: 19779-48-7.mol

Synonyms:Carbanilicacid, N-ethyldithio-, monoammonium salt (8CI)

Chemical Property of ethyl(phenyl)carbamodithioic acid

Chemical Property:

• Vapor Pressure: 0.00707mmHg at 25°C
• Boiling Point: 269.9°Cat760mmHg
• Flash Point: 117°C
• Density: 1.21g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ethyl(phenyl)carbamodithioic acid

There total 2 articles about ethyl(phenyl)carbamodithioic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

carbon disulfide (75-15-0,12122-00-8) + N-ethyl-N-phenylamine (103-69-5) → ammonium N-ethyl-N-phenyldithiocarbamate (19779-48-7)

Guidance literature:

With ammonia; water; Cooling with ice;

DOI:10.1016/j.poly.2010.01.011

Reference yield:

carbon disulfide (75-15-0,12122-00-8) + N,N-diphenylethylamine (606-99-5) → ammonium N-ethyl-N-phenyldithiocarbamate (19779-48-7)

Guidance literature:

N,N-diphenylethylamine; With ammonia; for 0.0833333h; Cooling with ice;

carbon disulfide; Cooling with ice;

DOI:10.1016/j.ica.2016.03.033

Reference yield: 98.0%

ammonium phenyldithiocarbamate (1074-52-8) + ammonium N-ethyl-N-phenyldithiocarbamate (19779-48-7) + cadmium(II) chloride (10108-64-2) → Cd(2+)*C7H6NS2(1-)*C9H10NS2(1-)

Guidance literature:

In water; at 20 ℃; for 1h;

DOI:10.1080/15533174.2015.1137589

upstream raw materials:

carbon disulfide

N-ethyl-N-phenylamine

N,N-diphenylethylamine

Downstream raw materials:

Cd(N-ethyl-N-phenyldithiocarbamate)(N-butyl-N-phenyldithiocarbamate)

Zn(N-ethyl-N-phenyldithiocarbamate)(N-butyl-N-phenyldithiocarbamate)

(mercury)(N-ethyl-N-phenyldithiocarbamate)(N-butyl-N-phenyldithiocarbamate)

Refernces

• 1、 Ajibade, Peter A.,Paca, Athandwe M.. "Bis-(N-ethylphenyldithiocarbamato)palladium(II) as molecular precursor for palladium sulfide nanoparticles". . . Retrieved 2021.
• 2、 Onwudiwe, Damian C.,Ajibade, Peter A.. "Synthesis and characterization of metal complexes of N-alkyl-N-phenyl dithiocarbamates". experimental part. p. 1431 - 1436. Retrieved 2010/05/01.