Micrococcin P, 13',19'-didehydro-19'-deoxy-28,44-dihydro-44-hydroxy-

Base Information

• Chemical Name: Micrococcin P, 13',19'-didehydro-19'-deoxy-28,44-dihydro-44-hydroxy-
• CAS No.: 67401-56-3
• Molecular Formula: C48H49N13O9S6
• Molecular Weight: 1144.46
• Mol file: 67401-56-3.mol

Synonyms:micrococcin;micrococcin P1

Chemical Property of Micrococcin P, 13',19'-didehydro-19'-deoxy-28,44-dihydro-44-hydroxy-

Chemical Property:

• Refractive Index: 1.6700 (estimate)
• PSA: 494.96000
• Density: 1.1650 (rough estimate)
• LogP: 7.66500
• XLogP3: 4.6
• Hydrogen Bond Donor Count: 9
• Hydrogen Bond Acceptor Count: 22
• Rotatable Bond Count: 10
• Exact Mass: 1143.21004723
• Heavy Atom Count: 76
• Complexity: 2180

Purity/Quality:

97% ^*data from raw suppliers

Micrococcin P1 ≥95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC=C1C2=NC(=CS2)C(=O)NC(C3=NC(=CS3)C(=O)NC(C4=NC(=CS4)C5=C(C=CC(=N5)C6=NC(=CS6)C7=NC(=CS7)C(=O)NC(=CC)C(=O)NCC(C)O)C8=NC(=CS8)C(=O)NC(C(=O)N1)C(C)O)C(C)O)C(C)C
• Isomeric SMILES: C/C=C/1\C2=NC(=CS2)C(=O)NC(C3=NC(=CS3)C(=O)NC(C4=NC(=CS4)C5=C(C=CC(=N5)C6=NC(=CS6)C7=NC(=CS7)C(=O)N/C(=C/C)/C(=O)NCC(C)O)C8=NC(=CS8)C(=O)NC(C(=O)N1)C(C)O)C(C)O)C(C)C
• Uses: Micrococcin P1 holds the remarkable position in antibiotic discovery as the first of the early antibiotics to be lost to science. Micrococcin P1 is a thiopeptide originally isolated from Micrococcus sp. by Su at Oxford in 1948. Later, Heatley and Doery purified micrococcin and defined its physico-chemical properties and activity. The producing strain was lost, causing a hiatus in research of this antibiotic family until the discovery of the related thiocillins in 1976.

Technology Process of Micrococcin P, 13',19'-didehydro-19'-deoxy-28,44-dihydro-44-hydroxy-

There total 2 articles about Micrococcin P, 13',19'-didehydro-19'-deoxy-28,44-dihydro-44-hydroxy- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C48H51N13O10S6*ClH → micrococcin P1 (67401-56-3)

Guidance literature:

With diphenyl phosphoryl azide; triethylamine; In N,N-dimethyl-formamide; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1002/anie.200900621

Reference yield:

C48H51N13O10S6 → micrococcin P1 (67401-56-3)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; ((3H-[1,2,3]triazolo[4,5-b]pyridin-3-yl)oxy)tri(pyrrolidin-1-yl)phosphonium hexafluorophosphate(V); In N,N-dimethyl-formamide; at -20 ℃; for 0.5h;

DOI:10.1039/C8SC04885A

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