dicyclopropyldiazene

Base Information

• Chemical Name: dicyclopropyldiazene
• CAS No.: 80201-75-8
• Molecular Formula: C6H10 N2
• Molecular Weight: 110.159
• Mol file: 80201-75-8.mol

Synonyms:dicyclopropyldiazene

Chemical Property of dicyclopropyldiazene

Chemical Property:

• Vapor Pressure: 7.37mmHg at 25°C
• Boiling Point: 141.3°C at 760 mmHg
• Flash Point: 30.3°C
• PSA: 24.72000
• Density: 1.35g/cm³
• LogP: 1.76340

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of dicyclopropyldiazene

There total 3 articles about dicyclopropyldiazene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

azoxycyclopropane (33425-51-3) → trans-azocyclopropane (80201-75-8)

Guidance literature:

With Si₂Cl₂;

DOI:10.1021/ja00415a066

Reference yield:

azoxycyclopropane (33425-51-3) → (cyclopropylazo)-n-propane (115962-97-5) + trans-azocyclopropane (80201-75-8)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; for 24h; Heating;

DOI:10.1021/jo00255a016

Reference yield:

cis-azocyclopropane (80201-76-9) → trans-azocyclopropane (80201-75-8)

Guidance literature:

In various solvent(s); at 200.2 ℃; Rate constant; Mechanism; ΔH (excit)= 36.2 kcal/mol^-1; ΔS(excit) = -3.3 eu;

DOI:10.1021/ja00415a066

upstream raw materials:

azoxycyclopropane

cis-azocyclopropane

Downstream raw materials:

tetramethyl-2,2,3,3 butane

2,2,4-trimethylpentane

ethane

ethene

Refernces

• 1、 Engel, Paul S.,Bodager, Gregory A.. "Photochemistry of Azocyclopropane". . p. 4748 - 4758. Retrieved 2007/10/02.