Methyl 2-O-methylfucofuranoside

Base Information

Chemical Name:Methyl 2-O-methylfucofuranoside
CAS No.:131065-17-3
Molecular Formula:C₈H₁₆O₅
Molecular Weight:192.212
Hs Code.:
DSSTox Substance ID:DTXSID30156862
Wikidata:Q83024977
Mol file:131065-17-3.mol

Synonyms:methyl 2-O-methyl-alpha-beta-L-fucofuranoside;methyl 2-O-methylfucofuranoside;methyl 2-O-methylfucofuranoside, beta-isomer;MMFFS

Suppliers and Price of Methyl 2-O-methylfucofuranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Methyl 2-O-methylfucofuranoside

Chemical Property:

Vapor Pressure:2.65E-05mmHg at 25°C
Boiling Point:320°Cat760mmHg
Flash Point:147.4°C
PSA：68.15000
Density:1.2g/cm³
LogP:-0.88560
XLogP3:-0.5
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:3
Exact Mass:192.09977361
Heavy Atom Count:13
Complexity:163

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C1C(C(C(O1)OC)OC)O)O
Isomeric SMILES:C[C@@H]([C@@H]1[C@H]([C@@H]([C@@H](O1)OC)OC)O)O

Technology Process of Methyl 2-O-methylfucofuranoside

There total 10 articles about Methyl 2-O-methylfucofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 131000-43-6,131000-46-9,131000-51-6,131021-85-7
methyl 5-O-benzyl-2-O-methyl-α,β-L-fucofuranoside

: 30021-73-9,131065-17-3,131065-19-5
methyl 2-O-methyl-α,β-L-fucofuranoside

Guidance literature:: With ammonia; lithium; In tetrahydrofuran; at -33 ℃; for 2h;
DOI:10.1016/0008-6215(90)80157-X

Reference yield:

: 5111-12-6
1,2-Isopropyliden-5-methyl-α-D-glucofuranosidurono-6,3-lacton

: 30021-73-9,131065-17-3,131065-19-5
methyl 2-O-methyl-α,β-L-fucofuranoside

Guidance literature:: Multi-step reaction with 10 steps

1: 84 percent / Amberlite IR-120 (H+) resin / 4 h / Heating

2: 60 percent / silver oxide / benzene

3: 71 percent / conc. HCl / Ambient temperature

4: 20percent di-isobutylaluminium hydride / CH₂Cl₂; hexane / 1 h / -78 °C

5: Amberlite IR-120(H+) resin / 3 h / Heating

6: 58 percent / W₂ Raney nickel / ethanol / 48 h

7: 72 percent / pyridine / 4 h / Ambient temperature

8: 75 percent / dimethylformamide / 40 h / 110 °C

9: 73 percent / sodium methoxide / methanol

10: 55 percent / liquid ammonia, Li-metal / tetrahydrofuran / 2 h / -33 °C

With pyridine; hydrogenchloride; diisobutylaluminum hydride; W₂ Raney nickel; Amberlite IR-120 (H+) resin; Amberlite IR-120(H+) resin; ammonia; sodium methylate; lithium; silver(l) oxide; In tetrahydrofuran; methanol; ethanol; hexane; dichloromethane; N,N-dimethyl-formamide; benzene;
DOI:10.1016/0008-6215(90)80157-X

Reference yield:

: 131000-39-0,131000-47-0
(3aS,6R,6aR)-6-Hydroxy-3,5-dimethoxy-tetrahydro-furo[3,2-b]furan-2-one

: 30021-73-9,131065-17-3,131065-19-5
methyl 2-O-methyl-α,β-L-fucofuranoside

Guidance literature:: Multi-step reaction with 9 steps

1: 60 percent / silver oxide / benzene

2: 71 percent / conc. HCl / Ambient temperature

3: 20percent di-isobutylaluminium hydride / CH₂Cl₂; hexane / 1 h / -78 °C

4: Amberlite IR-120(H+) resin / 3 h / Heating

5: 58 percent / W₂ Raney nickel / ethanol / 48 h

6: 72 percent / pyridine / 4 h / Ambient temperature

7: 75 percent / dimethylformamide / 40 h / 110 °C

8: 73 percent / sodium methoxide / methanol

9: 55 percent / liquid ammonia, Li-metal / tetrahydrofuran / 2 h / -33 °C

With pyridine; hydrogenchloride; diisobutylaluminum hydride; W₂ Raney nickel; Amberlite IR-120(H+) resin; ammonia; sodium methylate; lithium; silver(l) oxide; In tetrahydrofuran; methanol; ethanol; hexane; dichloromethane; N,N-dimethyl-formamide; benzene;
DOI:10.1016/0008-6215(90)80157-X