(+)-14-Epicorynoline

Base Information

Chemical Name:(+)-14-Epicorynoline
CAS No.:51151-82-7
Molecular Formula:C21H21NO5
Molecular Weight:367.4
Hs Code.:
Mol file:51151-82-7.mol

Synonyms:

Suppliers and Price of (+)-14-Epicorynoline

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of (+)-14-Epicorynoline

Chemical Property:

PSA：60.39000
LogP:2.44330

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Description The empirical formula for this alkaloid should read C21H21NO5

Technology Process of (+)-14-Epicorynoline

There total 20 articles about (+)-14-Epicorynoline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 55739-69-0,55781-75-4,61615-96-1,61615-97-2,70160-42-8,74708-05-7,74708-07-9
4bα,5,6,10b,11,12-hexahydro-5,10bα-dimethyl-2,3;7,8-bis(methylenedioxy)benzophenathridine-11α,12α-diol

: 18797-79-0,51095-71-7,51151-82-7,68035-45-0,70191-84-3,74163-86-3,83607-66-3,83607-67-4,112438-07-0,114580-51-7
(+/-)-11-epicorynoline

Guidance literature:: With hydrogenchloride; perchloric acid; hydrogen; palladium on activated charcoal; at 50 ℃; for 24h; under 3800 Torr;

Reference yield: 53.0%

: 55739-69-0,55781-75-4,61615-96-1,61615-97-2,70160-42-8,74708-05-7,74708-07-9
4bα,5,6,10b,11,12-hexahydro-5,10bα-dimethyl-2,3;7,8-bis(methylenedioxy)benzophenathridine-11α,12β-diol

: 18797-79-0,51095-71-7,51151-82-7,68035-45-0,70191-84-3,74163-86-3,83607-66-3,83607-67-4,112438-07-0,114580-51-7
(+/-)-11-epicorynoline

Guidance literature:: With hydrogenchloride; perchloric acid; hydrogen; palladium on activated charcoal; at 50 ℃; for 24h; under 3800 Torr;

Reference yield:

: 1207-57-4
3,4-dihydro-2-methyl-6,7-methylenedioxynaphthalen-1(2H)-one

: 18797-79-0,51095-71-7,51151-82-7,68035-45-0,70191-84-3,74163-86-3,83607-66-3,83607-67-4,112438-07-0,114580-51-7
(+/-)-11-epicorynoline

Guidance literature:: Multi-step reaction with 7 steps

1: 1.) titanium tetrachloride, 2.) triethylamine / 1.) chloroform, reflux, 1 h, 2.) benzene, 2 h

2: 20 percent / methanol / 16 h / Ambient temperature; Irradiation

3: 21 percent / hydrogen / palladium-charcoal / methanol / 2 h / 50 °C / 1900 Torr

4: 28 percent / dichlorodicyanobenzoquinone / CHCl₃ / 24 h / 4 °C

5: 1.) performic acid, 2.) sodium hydroxide / 1.) formic acid, room temperature, 1 h, 2.) methanol, reflux, 2 h

6: 83 percent / lithium aluminium hydride

7: 53 percent / hydrogen, hydrochloric acid, perchloric acid / palladium-charcoal / 24 h / 50 °C / 3800 Torr

With hydrogenchloride; sodium hydroxide; lithium aluminium tetrahydride; perchloric acid; Peroxyformic acid; hydrogen; titanium tetrachloride; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; palladium on activated charcoal; In methanol; chloroform;