Uvidin C

Base Information

Chemical Name:Uvidin C
CAS No.:74635-85-1
Molecular Formula:C₁₅H₂₆O₃
Molecular Weight:254.37
Hs Code.:
UNII:15L4YO5893
Nikkaji Number:J156.742J
Wikidata:Q27896702
Mol file:74635-85-1.mol

Synonyms:Uvidin C;(-)-Uvidin C;15L4YO5893;74635-85-1;UNII-15L4YO5893;Naphth(2,3-b)oxirene-2-methanol, decahydro-7-hydroxy-1a,2a,6,6-tetramethyl-, (1aR,2S,2aS,6aS,7S,7aS)-;Naphth(2,3-b)oxirene-2-methanol, decahydro-7-hydroxy-1a,2a,6,6-tetramethyl-, (1ar-(1aalpha,2beta,2abeta,6aalpha,7beta,7aalpha))-;Q27896702;NAPHTH(2,3-B)OXIRENE-2-METHANOL, DECAHYDRO-7-HYDROXY-1A,2A,6,6-TETRAMETHYL-, (1AR-(1A.ALPHA.,2.BETA.,2A.BETA.,6A.ALPHA.,7.BETA.,7A.ALPHA.))-

Suppliers and Price of Uvidin C

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Uvidin C

Chemical Property:

PSA：52.99000
LogP:1.95950
XLogP3:2.4
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:254.18819469
Heavy Atom Count:18
Complexity:367

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(CCCC2(C1C(C3C(C2CO)(O3)C)O)C)C
Isomeric SMILES:C[C@]12CCCC([C@@H]1[C@@H]([C@H]3[C@@]([C@@H]2CO)(O3)C)O)(C)C

Technology Process of Uvidin C

There total 19 articles about Uvidin C which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 110612-11-8
(1R,4S,4aR,8aS)-4-(Hydroxymethyl)-3,4a,8,8-tetramethyl-1,4,4a,5,6,7,8,8a-octahydronaphthalen-1-ol

: 74635-85-1
(-)-Uvidin C

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃; for 0.416667h;
DOI:10.1055/s-2000-8225

Reference yield:

: 111319-83-6
methyl bicyclofarnesate

: 74635-85-1
(-)-Uvidin C

Guidance literature:: Multi-step reaction with 9 steps

1: siglet oxigen

2: 79 percent / KOH / dioxane / Heating

3: 84 percent / methanesulfonic anhydride, Et₃N, DMAP / CH₂Cl₂ / 15 h / Heating

4: 81 percent / m-CpBA / CH₂Cl₂ / 35 h / 25 °C

5: 52 percent / Li/NH₃ / tetrahydrofuran / 0.5 h / -78 °C

6: PCC / CH₂Cl₂ / 2 h / 25 °C

7: 91 percent / DIBAL / tetrahydrofuran; hexane / 0.75 h / -5 °C

8: LiAlH₄ / diethyl ether

9: VO(acac)2/TBHP / CH₂Cl₂

With tert.-butylhydroperoxide; dmap; potassium hydroxide; lithium aluminium tetrahydride; bis(acetylacetonate)oxovanadium; siglet oxigen; ammonia; lithium; diisobutylaluminium hydride; triethylamine; 3-chloro-benzenecarboperoxoic acid; pyridinium chlorochromate; Methanesulfonic anhydride; In tetrahydrofuran; 1,4-dioxane; diethyl ether; hexane; dichloromethane;
DOI:10.1016/S0040-4039(00)98250-9

Reference yield:

: 105479-56-9
(1aR,2aS,6aS,7R,7aS)-3,3,6a,7a-Tetramethyl-decahydro-1-oxa-cyclopropa[b]naphthalene-7-carboxylic acid methyl ester

: 74635-85-1
(-)-Uvidin C

Guidance literature:: Multi-step reaction with 9 steps

1: LDA / tetrahydrofuran / 38 h / -78 - 25 °C

2: 79 percent / KOH / dioxane / Heating

3: 84 percent / methanesulfonic anhydride, Et₃N, DMAP / CH₂Cl₂ / 15 h / Heating

4: 81 percent / m-CpBA / CH₂Cl₂ / 35 h / 25 °C

5: 52 percent / Li/NH₃ / tetrahydrofuran / 0.5 h / -78 °C

6: PCC / CH₂Cl₂ / 2 h / 25 °C

7: 91 percent / DIBAL / tetrahydrofuran; hexane / 0.75 h / -5 °C

8: LiAlH₄ / diethyl ether

9: VO(acac)2/TBHP / CH₂Cl₂

With tert.-butylhydroperoxide; dmap; potassium hydroxide; lithium aluminium tetrahydride; bis(acetylacetonate)oxovanadium; ammonia; lithium; diisobutylaluminium hydride; triethylamine; 3-chloro-benzenecarboperoxoic acid; pyridinium chlorochromate; lithium diisopropyl amide; Methanesulfonic anhydride; In tetrahydrofuran; 1,4-dioxane; diethyl ether; hexane; dichloromethane;
DOI:10.1016/S0040-4039(00)98250-9