Silane, trimethyl(3-phenyl-2-propenyl)-, (Z)-

Base Information

• Chemical Name: Silane, trimethyl(3-phenyl-2-propenyl)-, (Z)-
• CAS No.: 40595-35-5
• Molecular Formula: C12H18Si
• Molecular Weight: 190.36
• Mol file: 40595-35-5.mol

Synonyms:40595-35-5;Silane, trimethyl(3-phenyl-2-propenyl)-, (Z)-;Silane,trimethyl(3-phenyl-2-propenyl)-,(Z)-

Chemical Property of Silane, trimethyl(3-phenyl-2-propenyl)-, (Z)-

Chemical Property:

• Vapor Pressure: 0.0503mmHg at 25°C
• Boiling Point: 243.4°C at 760 mmHg
• Flash Point: 88.2°C
• Density: 0.882g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 190.117777109
• Heavy Atom Count: 13
• Complexity: 159

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)CC=CC1=CC=CC=C1
• Isomeric SMILES: C[Si](C)(C)C/C=C\C1=CC=CC=C1

Technology Process of Silane, trimethyl(3-phenyl-2-propenyl)-, (Z)-

There total 31 articles about Silane, trimethyl(3-phenyl-2-propenyl)-, (Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

bis(tetrahydrofuran)tris(trimethylsilylmethyl)yttrium(III) + (Z)-β-bromostyrene (588-73-8,1340-14-3) → (Z)-1-phenyl-3-(trimethylsilyl)-1-propene (40595-35-5)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; In toluene; at 20 ℃; for 1h; Schlenk technique; Inert atmosphere;

DOI:10.1039/c6ob01765g

Reference yield: 91.0%

(1S,2S)-1-Phenyl-2,3-bis-trimethylsilanyl-propan-1-ol (104107-98-4) → (Z)-1-phenyl-3-(trimethylsilyl)-1-propene (40595-35-5)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide; for 15h; Heating;

DOI:10.1016/S0040-4039(00)76172-7

Reference yield: 73.0%

(trimethylsilyl)methylmagnesium chloride (13170-43-9) + (Z)-β-(methylselenyl)styrene (95391-81-4) → (Z)-1-phenyl-3-(trimethylsilyl)-1-propene (40595-35-5)

Guidance literature:

With bis(triphenylphosphine)nickel(II) chloride; In 1,2-dimethoxyethane; diethyl ether; for 3h; Heating;

DOI:10.1016/S0040-4039(00)73479-4

upstream raw materials:

2-(trimethylsilyl)ethyltriphenylphosphonium iodide

benzaldehyde

trimethylsilyllithium

Cinnamyl bromide

Downstream raw materials:

1-phenylpropene

(E)-trimethyl(3-phenylallyl)silane

anti-3-phenyl-4-hydroxy-1-pentene

(±)-(2R,3S)-3-phenylpent-4-en-2-ol