(1-Naphthylmethyl)triphenylphosphonium chloride

Base Information

• Chemical Name: (1-Naphthylmethyl)triphenylphosphonium chloride
• CAS No.: 23277-00-1
• Molecular Formula: C29H24 P . Cl
• Molecular Weight: 438.936
• Hs Code.: 29319019
• European Community (EC) Number: 245-548-3
• DSSTox Substance ID: DTXSID40945961
• Mol file: 23277-00-1.mol

Synonyms:23277-00-1;(1-Naphthylmethyl)triphenylphosphonium chloride;(naphthalen-1-ylmethyl)triphenylphosphonium chloride;naphthalen-1-ylmethyl(triphenyl)phosphanium chloride;naphthalen-1-ylmethyl(triphenyl)phosphanium;chloride;EINECS 245-548-3;Triphenyl(1-naphthylmethyl)phosphonium Chloride;1-naphthylmethyltriphenylphosphonium chloride;C29H24P.Cl;SCHEMBL723040;C29-H24-P.Cl;DTXSID40945961;MOYSMPXSEXYEJV-UHFFFAOYSA-M;Phosphonium, (1-naphthalenylmethyl)triphenyl-, chloride (1:1);MFCD00031658;AKOS015833182;CS-0186107;FT-0604523;FT-0608135;N0700;(1-napthylmethyl)triphenylphosphonium chloride;D91763;(1-Naphthylmethyl)-triphenylphosphonium chloride;(naphthalen-1-ylmethyl)triphenylphosphoniumchloride;1-naphthalenylmethyl(triphenyl)phosphonium chloride;A816652;J-015062;[(naphthalen-1-yl)methyl]triphenylphosphanium chloride;[(Naphthalen-1-yl)methyl](triphenyl)phosphanium chloride

Chemical Property of (1-Naphthylmethyl)triphenylphosphonium chloride

Chemical Property:

• Appearance/Colour: white crystalline powder.
• Melting Point: 300 °C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 13.59000
• Density: g/cm³
• LogP: 3.33790
• Storage Temp.: Inert atmosphere,Room Temperature
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 438.1304155
• Heavy Atom Count: 31
• Complexity: 463

Purity/Quality:

97% ^*data from raw suppliers

(Naphthalen-1-ylmethyl)triphenylphosphoniumChloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): XnXi
• Hazard Codes: Xn
• Statements: 36/37/38-22
• Safety Statements: 37/39-26-37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[P+](CC2=CC=CC3=CC=CC=C32)(C4=CC=CC=C4)C5=CC=CC=C5.[Cl-]

Technology Process of (1-Naphthylmethyl)triphenylphosphonium chloride

There total 2 articles about (1-Naphthylmethyl)triphenylphosphonium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

triphenylphosphine (603-35-0) + 1-Chloromethylnaphthalene (86-52-2) → 1-naphthylmethyltriphenylphosphonium chloride (23277-00-1)

Guidance literature:

In toluene; Reflux;

DOI:10.3390/molecules22122143

Reference yield:

→ 1-naphthylmethyltriphenylphosphonium chloride (23277-00-1)

Guidance literature:

/BRN= 636885/, PPh3 /DMF, Δ;

Reference yield: 99.0%

2-acetylbenzaldehyde (24257-93-0) + 1-naphthylmethyltriphenylphosphonium chloride (23277-00-1) → 1-(α-Naphthyl)-2-(2'-acetylphenyl)ethen

Guidance literature:

With potassium hydroxide; In chloroform;

DOI:10.1039/c6pp00089d

upstream raw materials:

triphenylphosphine

1-Chloromethylnaphthalene

Downstream raw materials:

1-vinylnaphthalene

1-Methyl-6-(1-naphthyl)-2,3,4-triphenyl-fulven

1-(4-Brommethyl-styryl)-naphthalin

(E)-1-(4-nitrostyryl)naphthalene