2-[[(2-Thiazolyl)imino]methyl]phenol

Base Information

Chemical Name:2-[[(2-Thiazolyl)imino]methyl]phenol
CAS No.:21151-43-9
Molecular Formula:C10H8N2OS
Molecular Weight:204.252
Hs Code.:
DSSTox Substance ID:DTXSID501297081
Nikkaji Number:J2.733.114I
Mol file:21151-43-9.mol

Synonyms:21151-43-9;salicylideneaminothiazole;Maybridge1_005262;Oprea1_364187;CBDivE_000766;DTXSID501297081;2-[(2-Thiazolylimino)methyl]phenol;2-[[(2-Thiazolyl)imino]methyl]phenol

Suppliers and Price of 2-[[(2-Thiazolyl)imino]methyl]phenol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of 2-[[(2-Thiazolyl)imino]methyl]phenol

Chemical Property:

Vapor Pressure:1.03E-05mmHg at 25°C
Boiling Point:371.5°C at 760 mmHg
Flash Point:178.5°C
Density:1.493g/cm³
XLogP3:2.2
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:204.03573406
Heavy Atom Count:14
Complexity:210

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C(=C1)C=NC2=NC=CS2)O

Technology Process of 2-[[(2-Thiazolyl)imino]methyl]phenol

There total 1 articles about 2-[[(2-Thiazolyl)imino]methyl]phenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 96-50-4
2-thiazolylamine

: 90-02-8
salicylaldehyde

: 21151-43-9
salicylidene-2-aminothiazole

Guidance literature:: In methanol; for 3h; Reflux; Inert atmosphere;
DOI:10.3390/molecules26195876

Reference yield: 90.0%

: 25246-23-5,19394-85-5,34723-98-3
mer-tricarbonyl-chloro-bis(triphenylphosphine)rhenium

: 21151-43-9
salicylidene-2-aminothiazole

: 123391-13-9
{Re(P(C₆H₅)3)2(CO)2{(C₃H₂NS)NCHC₆H₄O}}

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; addn. of a soln. of n-BuLi in hexane to a soln. of the ligand in dried THF, room temp., addn. of solid Re(PPh3)2(CO)3Cl to the soln., heating to boiling point, red soln., refluxed 1 h; concd. to one third of its volume, filtered, addn. of EtOH to the soln., pptn., washed (H2O, EtOH and EtOEt), crystd. (CH2Cl2/EtOH 7:3 vol/vol), elem. anal.;
DOI:10.1016/S0020-1693(00)85393-1

Reference yield: 85.0%

: 64396-16-3
[TcCl(CO)3(PPh₃)2]

: 21151-43-9
salicylidene-2-aminothiazole

: {Tc(P(C₆H₅)3)2(CO)2{(C₃H₂NS)NCHC₆H₄O}}

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; addn. of a soln. of n-BuLi in hexane to a soln. of the ligand in dried THF, room temp., addn. of solid Tc(PPh3)2(CO)3Cl to the soln., heating to boiling point, red soln., refluxed 1 h; concd. to one third of its volume, filtered, addn. of EtOH to the soln., pptn., washed (H2O, EtOH and EtOEt), crystd. (CH2Cl2/EtOH 7:3 vol/vol), elem. anal.;
DOI:10.1016/S0020-1693(00)85393-1