Bromopropylmagnesium

Base Information

• Chemical Name: Bromopropylmagnesium
• CAS No.: 927-77-5
• Molecular Formula: C3H7BrMg
• Molecular Weight: 147.298
• Hs Code.: 29319090
• European Community (EC) Number: 213-162-4
• Mol file: 927-77-5.mol

Synonyms:927-77-5;Propylmagnesium Bromide;Bromopropylmagnesium;n-propylmagnesium bromide;Propylmagnesiumbromide;Propylmagnesium Bromide (ca. 27% in Tetrahydrofuran, ca. 2mol/L);nPrMgBr;PrMgBr;n-PrMgBr;propyl magnesiumbromide;C3H7MgBr;propyl magnesium bromide;1-propylmagnesium bromide;n-propyl magnesium bromide;n-propyl-magnesium bromide;1-Propyl magnesium bromide;1-n-propylmagnesium bromide;SCHEMBL2399;(2-methylethyl)magnesium bromide;YQMARKZVVTYGOK-UHFFFAOYSA-M;EINECS 213-162-4;MFCD00058928;AKOS027469860;Propylmagnesium bromide, 1.0 M in THF;Magnesium, bromopropyl-(7CI,8CI,9CI);Propylmagnesium bromide, 1.0 M in 2-MeTHF

Chemical Property of Bromopropylmagnesium

Chemical Property:

• Melting Point: 61.5-62.5℃
• Boiling Point: 120-121 °C(Press: 0.2 Torr)
• Flash Point: -17°C (THF)
• PSA: 0.00000
• Density: 1,058 g/cm³
• LogP: 2.20960
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 145.95815
• Heavy Atom Count: 5
• Complexity: 6.9

Purity/Quality:

99% ^*data from raw suppliers

Propylmagnesium Bromide (ca. 27% in Tetrahydrofuran, ca. 2mol/L) ^*data from reagent suppliers

Safty Information:

• Statements: 11-15-19-34-37-36/37/38-14
• Safety Statements: 7/8-26-36/37/39-43-16

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Metals, Organic Compounds
• Canonical SMILES: CC[CH2-].[Mg+2].[Br-]
• Uses: Alkylating agent in organic synthesis.

Technology Process of Bromopropylmagnesium

There total 9 articles about Bromopropylmagnesium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

propyl bromide (106-94-5) → n-propylmagnesium bromide (927-77-5)

Guidance literature:

With magnesium; In diethyl ether; Thermodynamic data; -ΔH(reaction);

Reference yield:

Li2 CuCl4 + propyl bromide (106-94-5) → n-propylmagnesium bromide (927-77-5)

Guidance literature:

With CuCl₂; magnesium; lithium chloride; In tetrahydrofuran;

Reference yield:

dioxa-octyne + propyl bromide (106-94-5) → n-propylmagnesium bromide (927-77-5)

Guidance literature:

With ammonium chloride; magnesium; In tetrahydrofuran; water;

upstream raw materials:

propyl bromide

Downstream raw materials:

pentan-1-ol

hexan-1-ol

2-methylhexan-3-ol

6-propyl-2,3,4,5-tetrahydropyridine

Refernces

• 1、 Deng, Yuchao,Wei, Xiao-Jing,Wang, Xiao,Sun, Yuhan,No?l, Timothy. "Iron-Catalyzed Cross-Coupling of Alkynyl and Styrenyl Chlorides with Alkyl Grignard Reagents in Batch and Flow". supporting information. p. 14532 - 14535. Retrieved 2019/11/21.
• 2、 Novakov,Feierman,Cederbaum,Stoyanovsky. "An ESR and HPLC-EC assay for the detection of alkyl radicals". . p. 1239 - 1246. Retrieved 2007/10/03.