2,3,5-tris(methylsulfanyl)benzene-1,4-diol

Base Information

• Chemical Name: 2,3,5-tris(methylsulfanyl)benzene-1,4-diol
• CAS No.: 127087-16-5
• Molecular Formula: C9H12 O2 S3
• Molecular Weight: 248.391
• Mol file: 127087-16-5.mol

Synonyms:T 1801A

Chemical Property of 2,3,5-tris(methylsulfanyl)benzene-1,4-diol

Chemical Property:

• Vapor Pressure: 7.95E-05mmHg at 25°C
• Boiling Point: 331.7°C at 760 mmHg
• Flash Point: 161.5°C
• Density: 1.41g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,3,5-tris(methylsulfanyl)benzene-1,4-diol

There total 2 articles about 2,3,5-tris(methylsulfanyl)benzene-1,4-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Dimethyldisulphide (624-92-0) + 4-methoxy-phenol (150-76-5) → 4-methoxy-3-(methylthio)phenol (127087-14-3) + 2,3,5-tri(methylthio)hydroquinone (127087-16-5) + hydroquinone (123-31-9,8027-02-9)

Guidance literature:

With tert.-butyl lithium; tert-butyl alcohol; Yield given. Multistep reaction; 1) THF, pentane, room temp., 6 h; 2) room temp., 17 h;

DOI:10.1021/jo00299a038

Reference yield:

Dimethyldisulphide (624-92-0) + 4-methoxy-phenol (150-76-5) → 4-methoxy-3-(methylthio)phenol (127087-14-3) + 2,3,5-tri(methylthio)hydroquinone (127087-16-5) + hydroquinone (123-31-9,8027-02-9)

Guidance literature:

With tert.-butyl lithium; tert-butyl alcohol; In tetrahydrofuran; pentane; Product distribution; Ambient temperature; Multistep reaction: 1) 6 h; 2) 17 h. Other alkoxyphenols investigated;

DOI:10.1021/jo00299a038

upstream raw materials:

Dimethyldisulphide

4-methoxy-phenol

Refernces