10-phenylacridarsine

Base Information

• Chemical Name: 10-phenylacridarsine
• CAS No.: 28660-45-9
• Molecular Formula: C₁₉H₁₃As
• Molecular Weight: 316.234
• Hs Code.: 2902909090
• Mol file: 28660-45-9.mol

Synonyms:Dibenzo[b,e]arsenin,10-phenyl-

Chemical Property of 10-phenylacridarsine

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 2.52790

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 10-phenylacridarsine

There total 10 articles about 10-phenylacridarsine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

5-chloro-10-phenyl-5,10-dihydro-acridarsine (28660-48-2) → 10-phenyl-acridarsine (28660-45-9)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In toluene;

DOI:10.1016/S0040-4039(01)98445-X

Reference yield:

(2-aminophenyl)diphenylmethane (57259-32-2) → 10-phenyl-acridarsine (28660-45-9)

Guidance literature:

Multi-step reaction with 3 steps

1: (i) HNO₂, (ii) AsCl₃, CuBr, (iii) polyphosphoric acid

2: SO₂, HCl / CHCl₃

3: DBU / toluene

With hydrogenchloride; sulfur dioxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; In chloroform; toluene;

DOI:10.1016/S0040-4039(01)98445-X

Reference yield:

5-oxo-10-phenyl-5,10-dihydro-5λ5-acridarsin-5-ol (28660-47-1) → 10-phenyl-acridarsine (28660-45-9)

Guidance literature:

Multi-step reaction with 2 steps

1: SO₂, HCl / CHCl₃

2: DBU / toluene

With hydrogenchloride; sulfur dioxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; In chloroform; toluene;

DOI:10.1016/S0040-4039(01)98445-X

upstream raw materials:

10,10-dibenzyl-5-phenyl-5,10-dihydro-acridarsine

10,10-dibenzyl-3-methyl-5-phenyl-5,10-dihydro-acridarsine

5-chloro-10-phenyl-5,10-dihydro-acridarsine

10-benzyl-5-oxo-5,10-dihydro-5λ⁵-acridarsin-5-ol