4-nitro-1,2,3,6,7,8-hexahydropyrene

Base Information

• Chemical Name: 4-nitro-1,2,3,6,7,8-hexahydropyrene
• CAS No.: 88535-47-1
• Molecular Formula: C16H15NO2
• Molecular Weight: 253.2958
• Mol file: 88535-47-1.mol

Synonyms:4-Nitro-1,2,3,6,7,8-hexahydro-pyren;4-nitro-1,2,3,6,7,8-hexahydro-pyrene;

Chemical Property of 4-nitro-1,2,3,6,7,8-hexahydropyrene

Chemical Property:

• Vapor Pressure: 1.49E-08mmHg at 25°C
• Melting Point: 89.0 to 93.0 °C
• Boiling Point: 470°C at 760 mmHg
• Flash Point: 234.3°C
• PSA: 45.82000
• Density: 1.308g/cm³
• LogP: 4.24860

Purity/Quality:

99% ^*data from raw suppliers

4-Nitro-1,2,3,6,7,8-hexahydropyrene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-nitro-1,2,3,6,7,8-hexahydropyrene

There total 1 articles about 4-nitro-1,2,3,6,7,8-hexahydropyrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

1,2,3,6,7,8-hexahydropyrene (1732-13-4) → 4-nitro-1,2,3,6,7,8-hexahydropyrene (88535-47-1)

Guidance literature:

With copper(II) nitrate; In acetic anhydride; for 6h; Ambient temperature;

DOI:10.1002/recl.19871060403

Reference yield:

4-nitro-1,2,3,6,7,8-hexahydropyrene (88535-47-1) → pyren-4-ylamine (17075-03-5)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrachloro-<1,4>benzoquinone; xylene

2: ethanol; N₂H₄*H₂O; palladium/charcoal

With palladium on activated charcoal; ethanol; chloranil; hydrazine hydrate; xylene;

DOI:10.1016/S1464-1909(00)00102-7

upstream raw materials:

1,2,3,6,7,8-hexahydropyrene

Downstream raw materials:

pyren-4-ylamine

Refernces

• 1、 Braken-van Leersum, A. M. van den,Tintel, C.,Zelfde, M. van't,Cornelisse, J.,Lugtenburg, J.. "Spectroscopic and photochemical properties of mononitropyrenes". . p. 120 - 128. Retrieved 2007/10/02.