trans-Quinoline-5,6,7,8-dioxide

Base Information

Chemical Name:trans-Quinoline-5,6,7,8-dioxide
CAS No.:142129-81-5
Molecular Formula:C₉H₇NO₂
Molecular Weight:161.16
Hs Code.:
DSSTox Substance ID:DTXSID00931360
Mol file:142129-81-5.mol

Synonyms:trans-Quinoline-5,6,7,8-dioxide;142129-81-5;(2S,4R)-3,6-dioxa-9-azatetracyclo[6.4.0.02,4.05,7]dodeca-1(8),9,11-triene;CCRIS 4440;1a,1b,2a,6b-Tetrahydrobisoxireno(f,h)quinoline (1a-alpha,1b-beta,2a-beta,6b-alpha)-(+-)-;Bisoxireno(f,h)quinoline, 1a,1b,2a,6b-tetrahydro-, (1a-alpha,1b-beta,2a-beta,6b-alpha)-(+-)-;DTXSID00931360;(+-)-trans-5,6,7,8-Diepoxy-5,6,7,8-tetrahydroquinoline;1a,1b,2a,6b-Tetrahydrobisoxireno[f,h]quinoline;(+/-)-TRNAS-5,6,7,8-DIEPOXY-5,6,7,8-TETRAHYDROQUINOLINE

Suppliers and Price of trans-Quinoline-5,6,7,8-dioxide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of trans-Quinoline-5,6,7,8-dioxide

Chemical Property:

Vapor Pressure:0.000193mmHg at 25°C
Refractive Index:1.5050 (estimate)
Boiling Point:338.4°C at 760 mmHg
Flash Point:123.8°C
PSA：37.95000
Density:1.477g/cm³
LogP:0.97500
XLogP3:-0.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:0
Exact Mass:161.047678466
Heavy Atom Count:12
Complexity:233

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC2=C(C3C(O3)C4C2O4)N=C1
Isomeric SMILES:C1=CC2=C(C3C(O3)[C@H]4[C@H]2O4)N=C1

Technology Process of trans-Quinoline-5,6,7,8-dioxide

There total 8 articles about trans-Quinoline-5,6,7,8-dioxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 130536-37-7,135096-28-5,135096-21-8
quinoline 5,6-arene oxide

: 120917-18-2,137492-00-3,142129-81-5,142184-78-9
trans-5,6,7,8-diepoxy-5,6,7,8-tetrahydroquinoline

: (1aR,7bS)-1a,7b-Dihydro-1-oxa-4-aza-cyclopropa[a]naphthalene 4-oxide

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; Product distribution;
DOI:10.1039/c39890000163

Reference yield: 67.0%

: 137411-57-5
6-bromo-5-hydroxy-7,8-epoxy-5,6,7,8-tetrahydroquinoline

: 120917-18-2,137492-00-3,142129-81-5,142184-78-9
cis-5,6,7,8-diepoxy-5,6,7,8-tetrahydroquinoline

Guidance literature:: With sodium methylate; In tetrahydrofuran; 1) 0 deg C, 1 h, 2) RT, 4 h;

Reference yield: 56.0%

: 130536-39-9,158060-63-0
quinoline 7,8-arene oxide

: 120917-18-2,137492-00-3,142129-81-5,142184-78-9
trans-5,6,7,8-diepoxy-5,6,7,8-tetrahydroquinoline

Guidance literature:: With sodium hypochlorite; tetra(n-butyl)ammonium hydrogensulfate; In dichloromethane; for 48h; Product distribution; Ambient temperature;
DOI:10.1039/c39890000163