2',3'-Dihydro-phytomenadione

Base Information

Chemical Name:2',3'-Dihydro-phytomenadione
CAS No.:64236-23-3
Molecular Formula:C₃₁H₄₈O₂
Molecular Weight:452.721
Hs Code.:
DSSTox Substance ID:DTXSID10982782
Metabolomics Workbench ID:46705
ChEMBL ID:CHEMBL2068846
Mol file:64236-23-3.mol

Synonyms:2',3'-dihydrophylloquinone;dihydrophylloquinone;hydrophylloquinone

Suppliers and Price of 2',3'-Dihydro-phytomenadione

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
β,γ-DihydroVitaminK1
10mg
$ 7675.00

TRC
β,γ-DihydroVitaminK1
5mg
$ 4210.00

Total 7 raw suppliers

Chemical Property of 2',3'-Dihydro-phytomenadione

Chemical Property:

Vapor Pressure:6.94E-12mmHg at 25°C
Boiling Point:543.8°C at 760 mmHg
Flash Point:199.6°C
PSA：34.14000
Density:0.953g/cm³
LogP:9.23750
Storage Temp.:Hygroscopic, -20°C Freezer, Under inert atmosphere
Solubility.:Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
XLogP3:10.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:15
Exact Mass:452.365430770
Heavy Atom Count:33
Complexity:643

Purity/Quality:

97% ^*data from raw suppliers

β,γ-DihydroVitaminK1 ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1=C(C(=O)C2=CC=CC=C2C1=O)CCC(C)CCCC(C)CCCC(C)CCCC(C)C
Uses Vitamin K1 derivative; a compound formed during hydrogenation of oils containing Vitamin K1.

Technology Process of 2',3'-Dihydro-phytomenadione

There total 8 articles about 2',3'-Dihydro-phytomenadione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 127184-25-2
2-methyl-3-(1',2'-dihydrophytyl)-1,4-dimethoxynaphthalene

: 64236-23-3
2-methyl-3-(1',2'-dihydrophytyl)-1,4-naphthoquinone

Guidance literature:: With silver(II) oxide; nitric acid; In 1,4-dioxane; at 10 ℃; for 0.0333333h;
DOI:10.1021/jm00168a038

Reference yield:

: 53772-33-1
2-bromo-3-methyl-1,4-dimethoxynaphthalene

: 64236-23-3
2-methyl-3-(1',2'-dihydrophytyl)-1,4-naphthoquinone

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) n-BuLi / 1.) ether, 8 min, 2.) 30 min

2: 44 percent / H₂ / 10percent Pd/C / ethyl acetate / 20 h

3: AgO, HNO₃ / dioxane / 0.03 h / 10 °C

With silver(II) oxide; n-butyllithium; hydrogen; nitric acid; palladium on activated charcoal; In 1,4-dioxane; ethyl acetate;
DOI:10.1021/jm00168a038

Reference yield:

: 220904-29-0
3,7,11,15-tetramethyl-hexadec-2-en-1-al

: 64236-23-3
2-methyl-3-(1',2'-dihydrophytyl)-1,4-naphthoquinone

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) n-BuLi / 1.) ether, 8 min, 2.) 30 min

2: 44 percent / H₂ / 10percent Pd/C / ethyl acetate / 20 h

3: AgO, HNO₃ / dioxane / 0.03 h / 10 °C

With silver(II) oxide; n-butyllithium; hydrogen; nitric acid; palladium on activated charcoal; In 1,4-dioxane; ethyl acetate;
DOI:10.1021/jm00168a038