RehMapicroside

Base Information

Chemical Name:RehMapicroside
CAS No.:104056-82-8
Molecular Formula:C16H26 O8
Molecular Weight:346.378
Hs Code.:
Mol file:104056-82-8.mol

Synonyms:1-Cyclohexene-1-carboxylicacid, 3-(b-D-glucopyranosyloxy)-2,6,6-trimethyl-,(R)-; Rehmapicroside

Suppliers and Price of RehMapicroside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

DC Chemicals
Rehmapicroside >98%
20 mg
$ 280.00

Biorbyt Ltd
Rehmapicroside
10 mg
$ 654.50

Biorbyt Ltd
Rehmapicroside
5 mg
$ 513.40

Arctom
Rehmapicroside ≥98%
10mg
$ 340.91

Arctom
Rehmapicroside
5mg
$ 318.00

Total 24 raw suppliers

Chemical Property of RehMapicroside

Chemical Property:

Boiling Point:569.2±50.0 °C(Predicted)
PKA:4.53±0.60(Predicted)
PSA：136.68000
Density:1.39±0.1 g/cm3(Predicted)
LogP:-0.60740

Purity/Quality:

≥98% ^*data from raw suppliers

Rehmapicroside >98% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of RehMapicroside

There total 6 articles about RehMapicroside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 28120-76-5
methyl 2,6,6-trimethyl-3-oxocyclohex-1-ene-1-carboxylate

: 104056-82-8
(3R)-2,6,6-trimethyl-3-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxycyclohexene-1-carboxylic acid

Guidance literature:: Multi-step reaction with 4 steps

1: 6.7 g / NaBH₄ / methanol / 0.33 h / 0 °C

2: Hg(CN)2 / benzene; dioxane / 5 h / Heating

3: 0.5percent NaOMe / methanol / 0.25 h / 24 °C

4: 33 mg / 10percent aq. KOH / methanol / 12 h / 60 °C

With potassium hydroxide; sodium tetrahydroborate; sodium methylate; mercury(II) cyanide; In 1,4-dioxane; methanol; benzene;
DOI:10.1248/cpb.44.41

Reference yield:

: 91029-31-1
methyl 3-hydroxy-2,6,6-trimethylcyclohex-1-ene-1-carboxylate

: 104056-82-8
(3R)-2,6,6-trimethyl-3-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxycyclohexene-1-carboxylic acid

Guidance literature:: Multi-step reaction with 3 steps

1: Hg(CN)2 / benzene; dioxane / 5 h / Heating

2: 0.5percent NaOMe / methanol / 0.25 h / 24 °C

3: 33 mg / 10percent aq. KOH / methanol / 12 h / 60 °C

With potassium hydroxide; sodium methylate; mercury(II) cyanide; In 1,4-dioxane; methanol; benzene;
DOI:10.1248/cpb.44.41

Reference yield:

: 104112-12-1
methyl (3R)-3-hydroxy-2,6,6-trimethylcyclohex-1-ene-1-carboxylate

: 104056-82-8
(3R)-2,6,6-trimethyl-3-[(2R,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxycyclohexene-1-carboxylic acid

Guidance literature:: Multi-step reaction with 5 steps

1: 8 mg / CrO₃, pyridine / 1 h / 28 °C

2: 6.7 g / NaBH₄ / methanol / 0.33 h / 0 °C

3: Hg(CN)2 / benzene; dioxane / 5 h / Heating

4: 0.5percent NaOMe / methanol / 0.25 h / 24 °C

5: 33 mg / 10percent aq. KOH / methanol / 12 h / 60 °C

With pyridine; chromium(VI) oxide; potassium hydroxide; sodium tetrahydroborate; sodium methylate; mercury(II) cyanide; In 1,4-dioxane; methanol; benzene;
DOI:10.1248/cpb.44.41