Technology Process of methanesulfonic acid, 1,1,1-trifluoro-, ruthenium(5+) salt, ammoniate hydrate (1:1:5:1)
There total 4 articles about methanesulfonic acid, 1,1,1-trifluoro-, ruthenium(5+) salt, ammoniate hydrate (1:1:5:1) which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
neat (no solvent);
Ru complex dissolved in min. of warm 3M CF3SO3H but keeping pH below 1,filtered, equal vol. of 8 M CF3SO3H added to filtrate; filtrate cooled in refrigerator, solid collected, washed with ether, dried in vac.;
DOI:10.1021/ic00141a025
- Guidance literature:
-
With
H2O; CF3SO3H;
In
water;
dissolving Ru-compd. in 0.1 M aqueous soln. of CF3SO3H, cooling below 5°C, slow addn. of CF3SO3H with stirring, keeping below 5°C overnight; filtration, drying in air, washing (diethyl ether), storing over P4O10;
- Guidance literature:
-
With
trifluorormethanesulfonic acid;
In
water;
dissolving H2(18)O-labeled Ru(NH3)5OH2(3+) salt in deionized distilled water containing 0.01 mol/l CF3SO3H; reaction takes place at ambient pressure and at 6.0 - 25.0°C in dark thermostated vessel;; water exchange is determined via conversion of water to CO2 with guanidine hydrochloride;;
Kinetics;
