2-(2-Butenyloxy)benzaldehyde

Base Information

• Chemical Name: 2-(2-Butenyloxy)benzaldehyde
• CAS No.: 40359-61-3
• Molecular Formula: C11H12O2
• Molecular Weight: 176.215
• NSC Number: 299898
• DSSTox Substance ID: DTXSID60422108
• Nikkaji Number: J1.829.261K
• Wikidata: Q82233933
• Mol file: 40359-61-3.mol

Synonyms:NSC299898;40359-61-3;2-(2-Butenyloxy)benzaldehyde;DTXSID60422108;(e)-2-(but-2-enyloxy)benzaldehyde;AKOS000249174;NSC-299898

Chemical Property of 2-(2-Butenyloxy)benzaldehyde

Chemical Property:

• Vapor Pressure: 0.00179mmHg at 25°C
• Boiling Point: 292.8°C at 760 mmHg
• Flash Point: 129.3°C
• Density: 1.047g/cm³
• XLogP3: 2.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 176.083729621
• Heavy Atom Count: 13
• Complexity: 175

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC=CCOC1=CC=CC=C1C=O
• Isomeric SMILES: C/C=C/COC1=CC=CC=C1C=O

Technology Process of 2-(2-Butenyloxy)benzaldehyde

There total 5 articles about 2-(2-Butenyloxy)benzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

(E/Z)-crotyl bromide (4784-77-4,29576-14-5,39616-19-8) + salicylaldehyde (90-02-8) → 2-(but-2-en-1-yloxy)benzaldehyde (40359-61-3)

Guidance literature:

With potassium fluoride; In acetone; for 72h; Heating;

DOI:10.1246/bcsj.55.2450

Reference yield:

Te-4-fluorophenyl 2-(2-butenyloxy)tellurobenzoate (143565-07-5) → 2-(but-2-en-1-yloxy)benzaldehyde (40359-61-3) + 3-ethylchroman-4-one (57646-02-3) + 3-<1-<(4-fluorophenyl)telluro>ethyl>chromanone (143565-11-1)

Guidance literature:

With thiophenol; In chloroform-d1; at 8 ℃; for 0.5h; Title compound not separated from byproducts; Irradiation;

DOI:10.1021/ja00099a011

Reference yield:

C11H14O2 → 2-(but-2-en-1-yloxy)benzaldehyde (40359-61-3)

Guidance literature:

With sodium acetate; pyridinium chlorochromate; In dichloromethane; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1021/acs.orglett.0c00770

upstream raw materials:

(E/Z)-crotyl bromide

salicylaldehyde

Te-4-fluorophenyl 2-(2-butenyloxy)tellurobenzoate

methyl salicylate

Downstream raw materials:

4-methyl-2-(phenylimino)-1,2,3,4,4a,10b-hexahydro-5H-<1>benzopyrano<4,3-d><1,3>thiazine

4-methyl-2-(phenylimino)-1,2,3,4,4a,10b-hexahydro-5H-<1>benzopyrano<4,3-d><1,3>thiazine

C₁₂H₁₄O