1,2,3-Tri-o-acetyl-6-deoxy-6-iodo-4-o-(2,3,4,6-tetra-o-acetylhexopyranosyl)hexopyranose

Base Information

Chemical Name:1,2,3-Tri-o-acetyl-6-deoxy-6-iodo-4-o-(2,3,4,6-tetra-o-acetylhexopyranosyl)hexopyranose
CAS No.:28810-03-9
Molecular Formula:C₂₆H₃₅IO₁₇
Molecular Weight:746.458
Hs Code.:
NSC Number:105392
DSSTox Substance ID:DTXSID50295767
Mol file:28810-03-9.mol

Synonyms:28810-03-9;NSC105392;1,2,3-tri-o-acetyl-6-deoxy-6-iodo-4-o-(2,3,4,6-tetra-o-acetylhexopyranosyl)hexopyranose;DTXSID50295767;NSC-105392

Suppliers and Price of 1,2,3-Tri-o-acetyl-6-deoxy-6-iodo-4-o-(2,3,4,6-tetra-o-acetylhexopyranosyl)hexopyranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of 1,2,3-Tri-o-acetyl-6-deoxy-6-iodo-4-o-(2,3,4,6-tetra-o-acetylhexopyranosyl)hexopyranose

Chemical Property:

Vapor Pressure:7.19E-19mmHg at 25°C
Boiling Point:689.6°C at 760 mmHg
Flash Point:370.9°C
Density:1.55g/cm³
XLogP3:1.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:17
Rotatable Bond Count:18
Exact Mass:746.09190
Heavy Atom Count:44
Complexity:1090

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=O)OCC1C(C(C(C(O1)OC2C(OC(C(C2OC(=O)C)OC(=O)C)OC(=O)C)CI)OC(=O)C)OC(=O)C)OC(=O)C

Technology Process of 1,2,3-Tri-o-acetyl-6-deoxy-6-iodo-4-o-(2,3,4,6-tetra-o-acetylhexopyranosyl)hexopyranose

There total 7 articles about 1,2,3-Tri-o-acetyl-6-deoxy-6-iodo-4-o-(2,3,4,6-tetra-o-acetylhexopyranosyl)hexopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 28810-01-7
1,2,3-tri-O-acetyl-4-O-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-β-D-glucopyranose

: 28810-03-9
1,2,3-tri-O-acetyl-6-deoxy-6-iodo-4-O-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-β-D-glucopyranose

Guidance literature:: With 1H-imidazole; iodine; triphenylphosphine; In acetonitrile; at 90 ℃; for 0.0833333h;

Reference yield:

: 28868-67-9
2,3-di-O-acetyl-1,6-anhydro-4-O-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-β-D-glycopyranose

: 28810-03-9
1,2,3-tri-O-acetyl-6-deoxy-6-iodo-4-O-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-β-D-glucopyranose

Guidance literature:: Multi-step reaction with 4 steps

1: 6.7 g / ZrCl₄ / CH₂Cl₂ / 3 h / 60 °C

2: AcOH, Ac₂O / 12 h / 50 °C

3: HCl / methanol / 3 h / Ambient temperature

4: 80 percent / I₂, PPh₃, imidazole / acetonitrile / 0.08 h / 90 °C

With 1H-imidazole; hydrogenchloride; iodine; acetic anhydride; zirconium(IV) chloride; acetic acid; triphenylphosphine; In methanol; dichloromethane; acetonitrile;

Reference yield:

: 137887-18-4
hexa-O-acetyl-6-O-formylmaltosyl chloride

: 28810-03-9
1,2,3-tri-O-acetyl-6-deoxy-6-iodo-4-O-(2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl)-β-D-glucopyranose

Guidance literature:: Multi-step reaction with 3 steps

1: AcOH, Ac₂O / 12 h / 50 °C

2: HCl / methanol / 3 h / Ambient temperature

3: 80 percent / I₂, PPh₃, imidazole / acetonitrile / 0.08 h / 90 °C

With 1H-imidazole; hydrogenchloride; iodine; acetic anhydride; acetic acid; triphenylphosphine; In methanol; acetonitrile;