2-(4-Ethenylphenyl)oxirane

Base Information

• Chemical Name: 2-(4-Ethenylphenyl)oxirane
• CAS No.: 10431-61-5
• Molecular Formula: C10H10 O
• Molecular Weight: 146.189
• European Community (EC) Number: 233-910-3
• DSSTox Substance ID: DTXSID20908913
• Nikkaji Number: J212.390H
• Mol file: 10431-61-5.mol

Synonyms:2-(4-ethenylphenyl)oxirane;10431-61-5;p-(Epoxyethyl)styrene;EINECS 233-910-3;2-(4-vinylphenyl)oxirane;Oxirane, (4-ethenylphenyl)-;4-vinylstyrene oxide;(4-Ethenylphenyl)oxirane;SCHEMBL2038273;DTXSID20908913;MFCD30533807;SY286660;A853217

Chemical Property of 2-(4-Ethenylphenyl)oxirane

Chemical Property:

• Vapor Pressure: 0.0433mmHg at 25°C
• Boiling Point: 246.2°Cat760mmHg
• Flash Point: 98.4°C
• PSA: 12.53000
• Density: 1.087g/cm³
• LogP: 2.40090
• XLogP3: 2.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 146.073164938
• Heavy Atom Count: 11
• Complexity: 145

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC1=CC=C(C=C1)C2CO2

Technology Process of 2-(4-Ethenylphenyl)oxirane

There total 2 articles about 2-(4-Ethenylphenyl)oxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

4-vinyl-benzaldehyde (1791-26-0) + trimethylsulphonium iodide (2181-42-2) → p-divinylbenzene monoepoxide (10431-61-5)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; dimethyl sulfoxide; at 0 ℃; for 12h; Inert atmosphere;

DOI:10.1021/jacs.5b08440

Reference yield:

→ p-divinylbenzene monoepoxide (10431-61-5)

Guidance literature:

2-Chlor-1-<4-(2-bromethyl)-phenyl>-ethanol-(1), ethanol. KOH;

Reference yield: 96.0%

p-divinylbenzene monoepoxide (10431-61-5) → 1,4-bis(oxiran-2-yl)benzene (16832-58-9)

Guidance literature:

With dihydrogen peroxide; cobalt(II) acetate; In water; at 20 ℃; for 3h; Ionic liquid; Green chemistry;

DOI:10.1007/s13738-015-0695-8

upstream raw materials:

4-vinyl-benzaldehyde

trimethylsulphonium iodide

Downstream raw materials:

IDA-(p)-DVBMO

1,4-bis(oxiran-2-yl)benzene

2-(4-vinylphenyl)ethan-1-ol

Refernces