4AcNPhCHO azine

Base Information

• Chemical Name: 4AcNPhCHO azine
• CAS No.: 17745-84-5
• Molecular Formula: C18H18 N4 O2
• Molecular Weight: 322.367
• European Community (EC) Number: 241-740-6
• Mol file: 17745-84-5.mol

Synonyms:4AcNPhCHO azine;C18H18N4O2;4-Acetamidobenzyldehyde, azine;17745-84-5;N-[4-[(E)-[(E)-(4-acetamidophenyl)methylenehydrazono]methyl]phenyl]acetamide

Chemical Property of 4AcNPhCHO azine

Chemical Property:

• Melting Point: 309-310 °C (decomp)
• Boiling Point: 590.6°Cat760mmHg
• PKA: 14.40±0.70(Predicted)
• Flash Point: 311°C
• PSA: 82.92000
• Density: 1.16g/cm³
• LogP: 3.20240
• XLogP3: 1.6
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 5
• Exact Mass: 322.14297583
• Heavy Atom Count: 24
• Complexity: 429

Purity/Quality:

99% ^*data from raw suppliers

4-ACETAMIDOBENZALDEHYDE AZINE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)NC1=CC=C(C=C1)C=NN=CC2=CC=C(C=C2)NC(=O)C
• Isomeric SMILES: CC(=O)NC1=CC=C(C=C1)/C=N/N=C/C2=CC=C(C=C2)NC(=O)C

Technology Process of 4AcNPhCHO azine

There total 4 articles about 4AcNPhCHO azine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-(4-[2-(aminocarbonothionyl)hydrazono]methylphenyl)acetamide (104-06-3) → bis-(4-acetylamino-benzylidene)-hydrazine (17745-84-5)

Guidance literature:

Multi-step reaction with 2 steps

1: dihydrogen peroxide; acetic acid / 0.17 h / 0 °C

2: dimethylsulfoxide-d6 / 240 h / 20 °C

With dihydrogen peroxide; acetic acid; In dimethylsulfoxide-d6;

DOI:10.1021/acs.chemrestox.1c00164

Reference yield:

C10H12N4O3S → bis-(4-acetylamino-benzylidene)-hydrazine (17745-84-5)

Guidance literature:

In dimethylsulfoxide-d6; at 20 ℃; for 240h;

DOI:10.1021/acs.chemrestox.1c00164

Reference yield:

para-acetamidobenzaldehyde (122-85-0) → bis-(4-acetylamino-benzylidene)-hydrazine (17745-84-5)

Guidance literature:

With water; hydrazinium sulfate;

upstream raw materials:

bis-(4-amino-benzylidene)-hydrazine

acetic anhydride

para-acetamidobenzaldehyde

N-(4-[2-(aminocarbonothionyl)hydrazono]methylphenyl)acetamide

Downstream raw materials:

3,7-bis-(4-acetylamino-phenyl)-tetrahydro-[1,2,4]triazolo[1,2-a][1,2,4]triazole-1,5-dithione

Refernces