(3R,2S,4R)-1-Methylenedasycarpidan

Base Information

Chemical Name:(3R,2S,4R)-1-Methylenedasycarpidan
CAS No.:17463-46-6
Molecular Formula:C₁₈H₂₂N₂
Molecular Weight:266.3807
Hs Code.:
Nikkaji Number:J1.973.870A
Wikidata:Q105162632

Synonyms:(3R,2S,4R)-1-Methylenedasycarpidan

Suppliers and Price of (3R,2S,4R)-1-Methylenedasycarpidan

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of (3R,2S,4R)-1-Methylenedasycarpidan

Chemical Property:

Vapor Pressure:7.38E-08mmHg at 25°C
Boiling Point:437.6°C at 760 mmHg
Flash Point:218.5°C
Density:1.14g/cm³
XLogP3:3.5
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:266.178298710
Heavy Atom Count:20
Complexity:404

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCC1C2CCN(C1C3=C(C2=C)NC4=CC=CC=C43)C
Isomeric SMILES:CC[C@@H]1[C@@H]2CCN([C@H]1C3=C(C2=C)NC4=CC=CC=C43)C

Technology Process of (3R,2S,4R)-1-Methylenedasycarpidan

There total 79 articles about (3R,2S,4R)-1-Methylenedasycarpidan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: noruleine

: 517-81-7,17463-46-6,19775-50-9,19775-51-0
20-epiuleine

Guidance literature:: With sodium cyanoborohydride; In water; acetonitrile; at 20 ℃; for 0.66h;
DOI:10.1021/acs.joc.6b00240

Reference yield: 85.0%

: 99612-57-4
1,13-Dihydroulein-N^b-oxid

: 517-81-7,17463-46-6,19775-50-9,19775-51-0
Ulein

Guidance literature:: With trifluoroacetic anhydride; In dichloromethane; for 0.0333333h;

Reference yield: 83.0%

: 917-54-4
methyllithium

(+)-dasycarpidone: 2825-08-3,16530-89-5,18688-38-5,18700-27-1
(+)-dasycarpidone

: 517-81-7,17463-46-6,19775-50-9,19775-51-0
(+)-uleine

Guidance literature:: methyllithium; (+)-dasycarpidone; In tetrahydrofuran; at 0 ℃;

With trifluoroacetic acid; In dichloromethane; at 23 ℃; for 0.25h; enantioselective reaction;
DOI:10.1002/hlca.202100088