Aluminum, tris(diethyldithiocarbamato)-

Base Information

• Chemical Name: Aluminum, tris(diethyldithiocarbamato)-
• CAS No.: 110975-13-8
• Molecular Formula: C₁₅H₃₀AlN₃S₆
• Molecular Weight: 471.801
• DSSTox Substance ID: DTXSID70149430
• Mol file: 110975-13-8.mol

Synonyms:Tris(diethyldithiocarbamato)aluminum;Aluminum, tris(diethyldithiocarbamato)-;Carbamic acid, diethyldithio-, aluminum salt;Aluminum, tris(diethylcarbamodithioato-S,S')-, (OC-6-11)-;110975-13-8;C15H30AlN3S6;DTXSID70149430;C15-H30-Al-N3-S6;LS-16510

Chemical Property of Aluminum, tris(diethyldithiocarbamato)-

Chemical Property:

• Vapor Pressure: 1.1mmHg at 25°C
• Boiling Point: 176.4°C at 760 mmHg
• Flash Point: 60.5°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 6
• Exact Mass: 471.0579384
• Heavy Atom Count: 25
• Complexity: 73

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCN(CC)C(=S)[S-].CCN(CC)C(=S)[S-].CCN(CC)C(=S)[S-].[Al+3]

Technology Process of Aluminum, tris(diethyldithiocarbamato)-

There total 3 articles about Aluminum, tris(diethyldithiocarbamato)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

tris(N,N-diethyldithiocarbamato)antimony(III) (20673-30-7,1000068-51-8) + aluminium hydride etherate → tris(N,N-diethyldithiocarbamato)aluminium(III) complex (110975-13-8)

Guidance literature:

In diethyl ether; toluene; byproducts: Sb, H2; under Ar; std. Schlenk tecniques; cooled toluene soln. of Sb(S2CNEt2)3 added to Et2O soln. of ((Et2O)k*AlH3))(n) at -78°C; mixt. stirredand allowed to warm slowly over 4 h to room temp.; above 30°C solid formed; filtered; Et2O removed in vac.; crystals obtained at 4°C;

DOI:10.1016/S0020-1693(99)00480-6

Reference yield: 58.0%

{As((C2H5)2NCSS)3} (20393-93-5) + aluminium hydride etherate → tris(N,N-diethyldithiocarbamato)aluminium(III) complex (110975-13-8)

Guidance literature:

In diethyl ether; toluene; byproducts: As, H2; under Ar; std. Schlenk tecniques; cooled toluene soln. of As(S2CNEt2)3 added to Et2O soln. of ((Et2O)k*AlH3))nx) at -78°C; mixt. stirredand allowed to warm slowly over 4 h to room temp.; above 0°C brown suspn. formed; filtered; Et2O removed in vac.; crystals obtained at -25°C;

DOI:10.1016/S0020-1693(99)00480-6

Reference yield: 31.0%

bis(N,N-diethyldithiocarbamato)Se complex (35327-20-9) + trimethylaminealane (16842-00-5) → tris(N,N-diethyldithiocarbamato)aluminium(III) complex (110975-13-8)

Guidance literature:

In diethyl ether; byproducts: SeH2; under Ar; std. Schlenk tecniques; (Me3N*AlH3)2 dissolved in Et2O and cooled to -78°C; Se(S2CNEt2)2 added slowly; mixt. stirred and allowed to warm to room temp.; Et2O removed in vac.; THF added; filtered; over 4 wk at -25°C crystals grown; elem. anal; NMR;

DOI:10.1016/S0020-1693(99)00480-6

upstream raw materials:

bis(N,N-diethyldithiocarbamato)Se complex

trimethylaminealane

{As((C₂H₅)2NCSS)3}

tris(N,N-diethyldithiocarbamato)antimony(III)

Refernces