(1alpha,3alpha,5alpha,7alpha)-3,8,8-trimethyl-4-oxatricyclo[5.1.0.03,5]octane

Base Information

Chemical Name:(1alpha,3alpha,5alpha,7alpha)-3,8,8-trimethyl-4-oxatricyclo[5.1.0.03,5]octane
CAS No.:35671-18-2
Molecular Formula:C10H16 O
Molecular Weight:152.236
Hs Code.:
Mol file:35671-18-2.mol

Synonyms:4-Oxatricyclo[5.1.0.03,5]octane,3,8,8-trimethyl-, (1a,3a,5a,7a)-; (-)-b-3,4-Epoxycarane;3-Carene cis-epoxide; 3b,4b-Epoxycarane; b-3,4-Epoxycarane

Suppliers and Price of (1alpha,3alpha,5alpha,7alpha)-3,8,8-trimethyl-4-oxatricyclo[5.1.0.03,5]octane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 5 raw suppliers

Chemical Property of (1alpha,3alpha,5alpha,7alpha)-3,8,8-trimethyl-4-oxatricyclo[5.1.0.03,5]octane

Chemical Property:

Boiling Point:182.5°Cat760mmHg
Flash Point:51.8°C
PSA：12.53000
Density:1.027g/cm³
LogP:2.20990

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (1alpha,3alpha,5alpha,7alpha)-3,8,8-trimethyl-4-oxatricyclo[5.1.0.03,5]octane

There total 7 articles about (1alpha,3alpha,5alpha,7alpha)-3,8,8-trimethyl-4-oxatricyclo[5.1.0.03,5]octane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 498-15-7,19079-29-9
(+)-Δ³-carene

: 936-91-4,936-92-5,2225-98-1,21218-11-1,35671-18-2
(1S,7R)-3,8,8-Trimethyl-4-oxa-tricyclo[5.1.0.0^3,5]octane

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In chloroform;
DOI:10.1016/S0040-4039(00)74500-X

Reference yield: 80.0%

: 13466-78-9,19079-29-9
3-carene

: 936-91-4,936-92-5,2225-98-1,21218-11-1,35671-18-2
α-3,4-Epoxycarane

Guidance literature:: With diphenylphosphinic anhydride; dihydrogen peroxide; potassium carbonate; In tetrahydrofuran; at -5 ℃; for 20h;
DOI:10.1016/0040-4039(94)88260-6

Reference yield: 73.0%

: 20296-50-8,19079-29-9
δ-3-carene

: 35671-18-2
Δ-3-carene oxide

Guidance literature:: δ-3-carene; With N-Bromosuccinimide; dimethyl sulfoxide; at 10 ℃; for 0.583333h; Inert atmosphere;

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dimethyl sulfoxide; at 0 ℃; for 0.5h; Inert atmosphere;
DOI:10.1016/j.tetlet.2010.10.068