2,3-O-Isopropylideneerythrose

Base Information

• Chemical Name: 2,3-O-Isopropylideneerythrose
• CAS No.: 37669-01-5
• Molecular Formula: C7H12O4
• Molecular Weight: 160.17
• Hs Code.: 2932999099
• DSSTox Substance ID: DTXSID60191084
• Nikkaji Number: J329.577J
• Mol file: 37669-01-5.mol

Synonyms:2,3-IPDT;2,3-isopropylidene-L-erythrose;2,3-O-isopropylideneerythrose

Chemical Property of 2,3-O-Isopropylideneerythrose

Chemical Property:

• Vapor Pressure: 0.00375mmHg at 25°C
• Melting Point: 29-31 °C
• Boiling Point: 249.1°C at 760 mmHg
• PKA: 14.20±0.10(Predicted)
• Flash Point: 99.2°C
• PSA: 55.76000
• Density: 1.192g/cm³
• LogP: -0.30230
• XLogP3: -0.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 160.07355886
• Heavy Atom Count: 11
• Complexity: 155

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1(OC(C(O1)C=O)CO)C
• Isomeric SMILES: CC1(O[C@H]([C@H](O1)C=O)CO)C

Technology Process of 2,3-O-Isopropylideneerythrose

There total 3 articles about 2,3-O-Isopropylideneerythrose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

3,4-O-isopropylidine L-arabinopyranose (58645-35-5,58645-40-2,144216-75-1) → 2,3-O-isopropylidene-L-erythrose (37669-01-5)

Guidance literature:

With sodium periodate; In methanol; water; at 20 ℃;

DOI:10.1055/s-0036-1588343

Reference yield:

[(4S,5R)-2,2-Dimethyl-5-((E)-styryl)-[1,3]dioxolan-4-yl]-methanol (127743-12-8) → 2,3-O-isopropylidene-L-erythrose (37669-01-5)

Guidance literature:

With ozone; In methanol; at -78 ℃;

DOI:10.1016/S0040-4039(01)93504-X

Reference yield:

→ 2,3-O-isopropylidene-L-erythrose (37669-01-5)

Guidance literature:

upstream raw materials:

[(4S,5R)-2,2-Dimethyl-5-((E)-styryl)-[1,3]dioxolan-4-yl]-methanol

3,4-O-isopropylidine L-arabinopyranose

Downstream raw materials:

2,3-O-isopropylidene-β-L-erythrofuranosyl 2,3-O-isopropylidene-β-L-erythrofuranoside

(4S,5R)-2,2-dimethyl-4-hydroxymethyl-5-vinyl-1,3-dioxolane

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