Tris(4-chlorophenyl) phosphite

Base Information

• Chemical Name: Tris(4-chlorophenyl) phosphite
• CAS No.: 5679-61-8
• Molecular Formula: C18H12Cl3O3P
• Molecular Weight: 413.624
• DSSTox Substance ID: DTXSID60205337
• Nikkaji Number: J1.331.074B
• Wikidata: Q83078894
• Mol file: 5679-61-8.mol

Synonyms:Tris(4-chlorophenyl) phosphite;Phosphorous acid, tris(4-chlorophenyl) ester;5679-61-8;C18H12Cl3O3P;SCHEMBL593487;Tris-(4-chlor-phenyl)-phosphit;DTXSID60205337;AMGMFFUMIJRDGW-UHFFFAOYSA-N;Phosphorous acid tris(4-chlorophenyl) ester

Chemical Property of Tris(4-chlorophenyl) phosphite

Chemical Property:

• Vapor Pressure: 1.55E-07mmHg at 25°C
• Melting Point: 49 °C
• Boiling Point: 440.2°C at 760 mmHg
• Flash Point: 220°C
• PSA: 41.28000
• LogP: 7.41050
• XLogP3: 7.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 6
• Exact Mass: 411.958964
• Heavy Atom Count: 25
• Complexity: 323

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1OP(OC2=CC=C(C=C2)Cl)OC3=CC=C(C=C3)Cl)Cl

Technology Process of Tris(4-chlorophenyl) phosphite

There total 5 articles about Tris(4-chlorophenyl) phosphite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

4-chloro-phenol (106-48-9,82344-39-6) → tris(p-chlorophenyl)phosphite (5679-61-8)

Guidance literature:

4-chloro-phenol; With sodium hydride; In tetrahydrofuran; at 0 - 20 ℃; Inert atmosphere;

With triethylamine; phosphorus trichloride; In tetrahydrofuran; at 20 ℃; for 20h; Inert atmosphere;

DOI:10.1039/c001660h

Reference yield: 52.0%

4-chloro-phenol (106-48-9,82344-39-6) → tris(p-chlorophenyl)phosphite (5679-61-8) + tris(4-chlorophenyl) phosphate (3871-31-6)

Guidance literature:

With tetraethylammonium iodide; In acetonitrile; at 50 ℃; electrosynthesis;

DOI:10.1007/BF00863577

Reference yield:

4-chloro-phenol (106-48-9,82344-39-6) + phosphorus trichloride (7719-12-2,52843-90-0) → tris(p-chlorophenyl)phosphite (5679-61-8)

Guidance literature:

In acetonitrile; for 6h; Reflux;

DOI:10.1074/jbc.M114.591339

upstream raw materials:

4-chloro-phenol

phosphorus trichloride

Downstream raw materials:

N--carbamidsaeuremethylester

tri-(4-chlorophenyl) phosphite ozonide

(CO)3NiP(OC₆H₄Cl-p)3

[Ru((POC₆H₃Cl-4)(OC₆H₄Cl-4)2)2(P(OC₆H₄Cl-4)3)2]