(1-hydroxypropyl)mercury

Base Information

• Chemical Name: (1-hydroxypropyl)mercury
• CAS No.: 21467-84-5
• Molecular Formula: C3H7HgO
• Molecular Weight: 259.6771
• Mol file: 21467-84-5.mol

Synonyms:

Chemical Property of (1-hydroxypropyl)mercury

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (1-hydroxypropyl)mercury

There total 2 articles about (1-hydroxypropyl)mercury which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

8-quinolinol (148-24-3,24804-14-6) + propylmercury (1+); bromide (18257-68-6) → CH3CH2CH2(1-)*Hg(2+)*C9H6NO(1-)=CH3CH2CH2Hg(C9H6NO) + Propylmercurihydroxid (21467-84-5)

Guidance literature:

With Ag₂O; NaOH; NaH₂PO₄; In water; benzene; byproducts: AgBr; to aq. suspn. of PrHgBr added 1.5 equiv. of freshly prepd. Ag2O, stirred for several days, solid NaOH added up to 0.1 M, left to stand overnight, filtered, neutralized with HClO4, NaH2PO4, Na2HPO4 and 8-quinolinol (C6H6) added, dild., shaken for 30 min; org. layer analyzed by means of spectrophotometry;

DOI:10.1246/bcsj.57.2271

Reference yield:

8-quinolinol (148-24-3,24804-14-6) + propylmercury (1+); bromide (18257-68-6) → CH3CH2CH2(1-)*Hg(2+)*CH3COO(1-)=CH3CH2CH2Hg(CH3COO) + CH3CH2CH2(1-)*Hg(2+)*C9H6NO(1-)=CH3CH2CH2Hg(C9H6NO) + CH3CH2CH2(1-)*Hg(2+)*C9H6NO(1-)*OH(1-)=[CH3CH2CH2Hg(C9H6NO)(OH)](1-) + CH3CH2CH2(1-)*Hg(2+)*OH(1-)*CH3COO(1-)=[CH3CH2CH2Hg(OH)(CH3COO)](1-) + Propylmercurihydroxid (21467-84-5)

Guidance literature:

With sodium hydroxide; acetic acid; silver(l) oxide; In ethanol; water; byproducts: AgBr; to aq. suspn. of PrHgBr added 1.5 equiv. of freshly prepd. Ag2O, stirred for several days, solid NaOH added up to 0.1 M, left to stand overnight, filtered, neutralized with HClO4, AcOH, AcONa, NaClO4, and 8-quinolinol (EtOH) added, dild., kept for 1.5 h; analyzed by means of spectrophotometric and pH measurements;

DOI:10.1246/bcsj.57.2266

upstream raw materials:

8-quinolinol

propylmercury ⁽¹⁺⁾; bromide