zearalenone-4-glucopyranoside

Base Information

• Chemical Name: zearalenone-4-glucopyranoside
• CAS No.: 105088-14-0
• Molecular Formula: C₂₄H₃₂O₁₀
• Molecular Weight: 480.512
• Mol file: 105088-14-0.mol

Synonyms:1H-2-Benzoxacyclotetradecin-1,7(8H)-dione,14-(b-D-glucopyranosyloxy)-3,4,5,6,9,10-hexahydro-16-hydroxy-3-methyl-,[S-(E)]-; Zearalenone-4-O-glucoside; Zearalenone-4-O-b-D-glucopyranoside

Chemical Property of zearalenone-4-glucopyranoside

Chemical Property:

• Vapor Pressure: 3.17E-27mmHg at 25°C
• Boiling Point: 803.1°Cat760mmHg
• Flash Point: 273°C
• PSA: 162.98000
• Density: 1.331g/cm³
• LogP: 1.05270

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Zearalenone-4-O-β-D-glucopyranoside functions as a new masked Fusarium mycotoxin in cell suspension cultures.

Technology Process of zearalenone-4-glucopyranoside

There total 3 articles about zearalenone-4-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

(S)-zearalenone 4-O-2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside → zearalenone-14-β-D-glucoside (105088-14-0)

Guidance literature:

With ion exchange resin (Dowex); In ethanol; water; for 120h;

DOI:10.1055/s-1992-26306

Reference yield:

zearalenone (17924-92-4,7645-23-0) → zearalenone-14-β-D-glucoside (105088-14-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 98 percent / tetra-n-butylammonium bromide, borate buffer / CHCl₃ / 2 h / 52 °C

2: 77 percent / ion exchange resin (Dowex) / ethanol; H₂O / 120 h

With borate buffer; ion exchange resin (Dowex); tetrabutylammomium bromide; In ethanol; chloroform; water;

DOI:10.1055/s-1992-26306

Reference yield:

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide (572-09-8) → zearalenone-14-β-D-glucoside (105088-14-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 98 percent / tetra-n-butylammonium bromide, borate buffer / CHCl₃ / 2 h / 52 °C

2: 77 percent / ion exchange resin (Dowex) / ethanol; H₂O / 120 h

With borate buffer; ion exchange resin (Dowex); tetrabutylammomium bromide; In ethanol; chloroform; water;

DOI:10.1055/s-1992-26306

upstream raw materials:

zearalenone

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

Refernces