1H-Phosphole, 1-phenyl-

Base Information

• Chemical Name: 1H-Phosphole, 1-phenyl-
• CAS No.: 20342-00-1
• Molecular Formula: C10H9P
• Molecular Weight: 160.155
• DSSTox Substance ID: DTXSID60174251
• Nikkaji Number: J258.920F
• Mol file: 20342-00-1.mol

Synonyms:1H-Phosphole, 1-phenyl-;20342-00-1;1-phenyl-1H-phosphole;1-phenylphosphole;1H-Phosphole,1-phenyl-;SCHEMBL4596245;DTXSID60174251;InChI=1/C10H9P/c1-2-6-10(7-3-1)11-8-4-5-9-11/h1-9

Chemical Property of 1H-Phosphole, 1-phenyl-

Chemical Property:

• Boiling Point: 64-65 °C(Press: 0.4 Torr)
• PSA: 0.00000
• LogP: 3.66240
• XLogP3: 2.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 160.044187285
• Heavy Atom Count: 11
• Complexity: 110

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P2C=CC=C2

Technology Process of 1H-Phosphole, 1-phenyl-

There total 6 articles about 1H-Phosphole, 1-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

1,4-dichloro-1,3-butadiene (2984-42-1) + dilithium phenylphosphide (13595-56-7,51918-34-4) → 1-Phenylphosphole (20342-00-1)

Guidance literature:

In diethyl ether; hexane; at 25 ℃; for 1h;

Reference yield:

1-Bromo-1-phenyl-2,5-dihydro-1H-phospholium; bromide → 1-Phenylphosphole (20342-00-1)

Guidance literature:

With α-picoline; In hexane; dichloromethane; Yield given; Ambient temperature;

DOI:10.1055/s-1981-29670

Reference yield:

phenyldibromophosphine (1073-47-8) → 1-Phenylphosphole (20342-00-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 2 h / 25 °C / 5250420 Torr

2: 2-methylpyridine / CH₂Cl₂; hexane / 1 h

With α-picoline; In hexane; dichloromethane;

DOI:10.1055/s-1989-27451

upstream raw materials:

1,4-dichloro-1,3-butadiene

dilithium phenylphosphide

phenyldibromophosphine

1-phenyl-3-phospholene 1-oxide

Downstream raw materials:

benzyl-1-phosphole

2-Phenyl-2-phosphabicyclo<3.1.0>hex-3-en

2,7-diphenyl-2,3-dihydro-[1,2]oxaphosphepine 2-oxide

2-phenylphospha-1-ferrocen